Polycyclic Aromatic Compounds ( IF 2.4 ) Pub Date : 2020-05-13 Raziyeh Bakhshali-Dehkordi, Mohammad Ali Ghasemzadeh, Javad Safaei-Ghomi
In this study, triazoloquinazolinone and benzimidazoquinazolinone derivatives have been synthesized via a suitable and efficient procedure using one-pot multicomponent reactions of 3-amino-1,2,4-triazole or 2-aminobenzimidazole, dimedone and aromatic aldehydes in the presence of TiO2@ILs as an efficient nanocatalyst. In the presented approach all of the products were prepared with good to excellent yields using TiO2@ILs nanostructures. Moreover, the TiO2 NPs were prepared using beet juice extract and functionalized with ILs based on imidazole. TiO2@ILs nanocatalyst has been characterized by different techniques such as Fourier transforms infrared, thermogravimetric analysis, X-ray diffraction, scanning electron microscope and energy-dispersive X-ray spectroscopy. Moreover, this ionic liquid presented itself as a good protective and activator agent for nanocatalyst.
中文翻译:
TiO2纳米粒子负载离子液体的多组分制备喹唑啉酮衍生物
在这项研究中,三唑基喹唑啉酮和苯并咪唑基喹唑啉酮衍生物是通过合适且有效的方法合成的,在TiO 2存在下,通过一锅多组分的3-氨基-1,2,4-三唑或2-氨基苯并咪唑,二甲酮和芳香醛进行反应@ILs是一种有效的纳米催化剂。在提出的方法中,使用TiO 2 @ILs纳米结构以良好或优异的产率制备了所有产品。此外,使用甜菜汁提取物制备了TiO 2 NP,并用基于咪唑的IL进行了功能化。二氧化钛2@ILs纳米催化剂已通过多种技术进行了表征,例如傅立叶变换红外光谱,热重分析,X射线衍射,扫描电子显微镜和能量色散X射线光谱。而且,该离子液体本身表现为纳米催化剂的良好保护和活化剂。