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A 3-D porous NiII coordination polymer constructed from oxalate and hydrazine linkers
Journal of Coordination Chemistry ( IF 2.2 ) Pub Date : 2020-05-13
Peng-Fei Yao, Jun-Rong Meng, Jie Tang, Jun-Bo Huang, Hai-Ye Li, Han-Fu Liu, He-Dong Bian, Fu-Ping Huang

A NiII-MOF, {[Ni(C2O4)(N2H4)]·2H2O}n (1), was constructed by oxalate and hydrazine under hydrothermal conditions at 130 °C. Single-crystal X-ray structural analysis indicates that 1 has a 3-D porous architecture with (103) topology based on two kinds of 1-D zigzag [Ni(C2O4)]n chains with the same structure but different extension directions in the ab plane separated by N2H4 linker. 1 reveals antiferromagnetic behavior and thermal stability below 283 °C.



中文翻译:

由草酸酯和肼连接基构建的3-D多孔NiII配位聚合物

在水热条件下于130°C的温度下通过草酸酯和肼构建Ni II -MOF,{[Ni(C 2 O 4)(N 2 H 4)]·2H 2 O} n1)。单晶X-射线结构分析表明1具有(10 3-d多孔结构3)拓扑基于2种1-d锯齿[镍(C的2 Ò 4)] Ñ具有相同的结构链,但不同的a 2平面中由N 2 H 4接头隔开的延伸方向。1个 揭示了在283°C以下的反铁磁行为和热稳定性。

更新日期:2020-05-13
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