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Molecular Sieve-Modified Separator for High-Performance Lithium-Ion Batteries.
Nanoscale Research Letters ( IF 5.5 ) Pub Date : 2020-05-13 , DOI: 10.1186/s11671-020-03327-8
Yuqiong Kang 1 , Changjian Deng 2 , Zhengyang Wang 1 , Yuqing Chen 1 , Xinyi Liu 3 , Zheng Liang 4 , Tao Li 3 , Quan Hu 5 , Yun Zhao 1, 3
Affiliation  

Lithium-ion batteries (LIBs) are currently the most important energy storage system. Separators in the battery play a critical role in terms of the rate capability, cycle life, and safe operation. However, commercial separators exhibit poor electrolyte wettability and limited safety. It is also extremely important to eliminate the hazardous small molecules (e.g., H2O and HF) inside the battery to enhance the service life. Herein, a functionalized poly(vinylidene fluoride-co-hexafluoropropylene)@polyacrylonitrile (PVDF-HFP@PAN) separator modified by 4-Å molecular sieves (MS) was fabricated by hydrothermal method for LIBs. MS@PVDF-HFP@PAN separator exhibits high thermal stability and carbonate electrolyte wettability. In addition, it can lower the moisture value in the battery system to 13 ppm, which significantly improves the electrolyte quality. When the current density increased from 0.2 to 5 C, the discharging capacity of the cell with MS@PVDF-HFP@PAN declines from 177.6 to 143.2 mAh g-1, demonstrating an excellent capacity retention of 80.6%. The discharge capacity retention of NMC622 half-cell with MS@PVDF-HFP@PAN after 100 cycles is 98.6% of its initial discharge capacity, which is higher than that of a cell with the Celgard 2400 separator (91.9%).

中文翻译:


用于高性能锂离子电池的分子筛改性隔膜。



锂离子电池(LIB)是目前最重要的储能系统。电池中的隔膜在倍率性能、循环寿命和安全运行方面起着至关重要的作用。然而,商用隔膜的电解质润湿性较差且安全性有限。消除电池内部的有害小分子(例如H2O和HF)对于延长使用寿命也极其重要。在此,通过水热法制备了经4-Å分子筛(MS)改性的功能化聚(偏二氟乙烯-六氟丙烯)@聚丙烯腈(PVDF-HFP@PAN)隔膜。 MS@PVDF-HFP@PAN隔膜具有较高的热稳定性和碳酸盐电解质润湿性。此外,它还可以将电池系统中的水分值降低至13 ppm,从而显着提高电解液质量。当电流密度从0.2 C增加到5 C时,MS@PVDF-HFP@PAN电池的放电容量从177.6 mAh g-1下降到143.2 mAh g-1,表现出80.6%的优异容量保持率。使用MS@PVDF-HFP@PAN的NMC622半电池在100次循环后的放电容量保持率为初始放电容量的98.6%,高于使用Celgard 2400隔膜的电池的放电容量保持率(91.9%)。
更新日期:2020-05-13
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