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The Formation of Me(AOT)n Micelles as Nanoreactors, Crystallizers, and Charging Agents: Cation-Exchange Solvent Extraction versus Direct Injection Solubilization
Solvent Extraction and Ion Exchange ( IF 1.8 ) Pub Date : 2020-03-09 , DOI: 10.1080/07366299.2020.1733747
Alexander I. Bulavchenko 1 , Tatyana Yu. Podlipskaya 1 , Marina G. Demidova 1 , Evgeniya A. Terzi 1 , Darya I. Beketova 1 , Nina F. Beisel 1
Affiliation  

The composition and hydrodynamic diameter of reverse micelles Me(AOT)n (n = 1–3) were determined during injection solubilization of nitrate salts of Li+, Na+, K+, Cs+, NH4+, Ag+, Ni2+, Co2+, Zn2+, Cu2+, Cd2+, Ca2+, Al3+, Fe3+, and La3+ cations and upon solvent extraction from their concentrated (1‒2 mol/L) solutions. It was found that solvent extraction by NaAOT reverse micelles can increase the concentration of cations in microemulsion by a factor of 10‒20 as compared to injection solubilization. Therewith, the fraction of super equivalent extraction of cations as nitrate salts into the aqueous cores of reverse micelles can reach 150%. According to the study, the higher is the hydration energy of cation, the greater is the number of successive extraction steps (up to 4) required for a virtually complete (more than 99%) replacement of Na+ in AOT micelles. The hydrodynamic diameter of Мe(AOT)n micelles was in the range from 3.2 to 13.9 nm, and the content of aqueous pseudophase, from 1.2 to 10.4 vol.%. It was demonstrated that the obtained extracts could be used for enhancing the productivity of micellar synthesis of nanoparticles (Ag and CdS) and isothermal micellar crystallization of salts (LiNO3, KNO3, CsNO3), and also as the charging agents (Cu(AOT)2, Ni(AOT)2, and Fe(АОТ)3) of SiO2 nanoparticles in the n-hexadecane-chloroform mixture.



中文翻译:

Me(AOT)n胶束作为纳米反应器,结晶剂和充电剂的形成:阳离子交换溶剂萃取与直接注射增溶

在注入溶解Li +,Na +,K +,Cs +,NH 4 +,Ag +,Ni 2的硝酸盐的过程中,确定了反胶束Me(AOT)nn = 1-3)的组成和流体动力学直径。+,Co 2 +,Zn 2 +,Cu 2 +,Cd 2 +,Ca 2 +,Al 3+,Fe 3+La 3+阳离子,并从浓溶液(1‒2 mol / L)中萃取溶剂。研究发现,与注射增溶相比,NaAOT反胶束萃取溶剂可使微乳液中阳离子的浓度增加10‒20。从而,将阳离子作为硝酸盐的超当量萃取到反胶束的水芯中的比例可达到150%。根据研究,阳离子的水合能量越高,AOT胶束中Na +的几乎完全替代(超过99%)所需的连续萃取步骤(最多4个)的数量就越大。Мe(AOT)n的流体力学直径胶束的范围为3.2至13.9nm,假水相的含量为1.2至10.4vol。%。结果表明,所得提取物可用于提高纳米颗粒(AgCdS)的胶束合成的生产率以及盐(LiNO 3,KNO 3,CsNO 3)的等温胶束结晶,还可以用作荷电剂(Cu(十六烷-氯仿混合物中SiO 2纳米颗粒的AOT)2,Ni(AOT)2Fe(АОТ)3)。

更新日期:2020-03-09
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