ABSTRACT Questions are raised concerning a previously published Abraham model correlation for describing the direct partitioning behaviour of solutes between water and 2,2,5,5-tetramethyloxolane. Numerous errors were found in the numerical values of the solute descriptors used in deriving the published correlation. The Abraham model correlation has been re-determined using the corrected solute descriptors. Principal Component Analysis of our derived water-to-2,2,5,5-tetramethyloxolane correlation with Abraham model correlations for other water-to-organic solvent partition systems confirms the suggestion of Byrne and co-workers that the green solvent 2,2,5,5-tetramethyloxolane can replace the solvent toluene, certainly as far as partition-related processes are concerned.

中文翻译：

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重新审视直接水到 2,2,5,5-四甲基氧戊环溶质转移分配过程的 Abraham 模型相关性

摘要 提出了关于先前公布的亚伯拉罕模型相关性的问题，该相关性用于描述水和 2,2,5,5-四甲基氧戊环之间的溶质直接分配行为。在用于推导已发表相关性的溶质描述符的数值中发现了许多错误。使用更正的溶质描述符重新确定了 Abraham 模型相关性。我们导出的水与 2,2,5,5-四甲基氧杂环戊烷相关性与其他水与有机溶剂分配系统的 Abraham 模型相关性的主成分分析证实了 Byrne 和同事的建议，即绿色溶剂 2,2 ,5,5-四甲基氧戊环可以代替溶剂甲苯，当然就分配相关的过程而言。