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X-ray powder diffraction data for three new 3-ethylanilinium molybdates
Powder Diffraction ( IF 0.3 ) Pub Date : 2020-04-29 , DOI: 10.1017/s0885715620000123 Alicja Rafalska-Łasocha , Michał Duda , Wiesław Łasocha
Powder Diffraction ( IF 0.3 ) Pub Date : 2020-04-29 , DOI: 10.1017/s0885715620000123 Alicja Rafalska-Łasocha , Michał Duda , Wiesław Łasocha
X-ray powder diffraction data for new metal-organic compounds: tetrakis(3-ethylanilinium) octamolybdate Mo8 O26 (C8 H12 N)4 [a = 10.682(4), b = 16.589(5), c = 7.307(2) Å, α = 92.79(2)°, β = 97.99(3)°, γ = 103.89(3)°, V = 1240.27 Å3 , Z = 1, space group P− 1]; tetrakis(3-ethylanilinium) octamolybdate tetrahydrate Mo8 O26 (C8 H12 N)4 ·(H2 O)4 [a = 18.801(7), b = 17.943(6), c = 7.334(3) Å, β = 98.50(5)°, V = 2446.99 Å3 , Z = 2, space group P 21 /m ] and bis(3-ethylanilinium) pentamolybdate Mo5 O16 (C8 H12 N)2 [a = 34.643(6), b = 5.5796(7), c = 14.200(3) Å, β = 96.20(2)°, V = 2728.69 Å3 , Z = 4, space group I 2/a ] are reported in this paper. The investigated compounds were synthesized from molybdic acid and 3-ethylaniline in acidic solution. In the first two cases, we obtained octamolybdates, while the last compound crystallized as pentamolybdate.
中文翻译:
三种新型 3-乙基苯胺钼酸盐的 X 射线粉末衍射数据
新金属有机化合物的 X 射线粉末衍射数据:四(3-乙基苯胺)八钼酸盐 Mo8 ○26 (C8 H12 N)4 [一种 = 10.682(4),b = 16.589(5),C = 7.307(2) 埃,α = 92.79(2)°,β = 97.99(3)°,γ = 103.89(3)°,五 = 1240.27 埃3 ,Z = 1,空间群P- 1]; 四(3-乙基苯胺)八钼酸盐四水合物 Mo8 ○26 (C8 H12 N)4 ·(H2 ○)4 [一种 = 18.801(7),b = 17.943(6),C = 7.334(3)埃,β = 98.50(5)°,五 = 2446.99 埃3 ,Z = 2,空间群磷 21 /米 ] 和双(3-乙基苯胺)五钼酸盐 Mo5 ○16 (C8 H12 N)2 [一种 = 34.643(6),b = 5.5796(7),C = 14.200(3) 埃,β = 96.20(2)°,五 = 2728.69 埃3 ,Z = 4,空间群一世 2/一种 ] 本文报道。所研究的化合物是由钼酸和 3-乙基苯胺在酸性溶液中合成的。在前两种情况下,我们得到了八钼酸盐,而最后一种化合物结晶为五钼酸盐。
更新日期:2020-04-29
中文翻译:
三种新型 3-乙基苯胺钼酸盐的 X 射线粉末衍射数据
新金属有机化合物的 X 射线粉末衍射数据:四(3-乙基苯胺)八钼酸盐 Mo