The development of chiral boron Lewis acids is highly essential for the chemistry of frustrated Lewis pairs. Three protocols including hydroboration, substitution and in situ hydroboration, have been successfully established to access the chiral boron Lewis acids. A rapid growth for the metal‐free asymmetric hydrogenation and hydrosilylation has therefore been achieved in the past decade. More details are discussed in the article by Du et al. on page 625—634.

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封底

手性硼路易斯酸的发展对于沮丧的路易斯对的化学反应非常重要。已经成功地建立了包括硼氢化，取代和原位硼氢化的三种方案来获得手性硼路易斯酸。因此，在过去的十年中，无金属不对称氢化和氢化硅烷化得到了快速发展。Du等人在文章中讨论了更多细节。在第625-634页。