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Properties of one-part fly ash/slag-based binders activated by thermally-treated waste glass/NaOH blends: A comparative study
Cement and Concrete Composites ( IF 10.8 ) Pub Date : 2020-05-12 , DOI: 10.1016/j.cemconcomp.2020.103679
M.H. Samarakoon , P.G. Ranjith , Wen Hui Duan , V.R.S. De Silva

Inclusion of a blend of soda-lime glass powder and sodium hydroxide as an alternative dry activator (DA) powder in fly ash/slag-based one-part alkali-activated materials (AAMs) was investigated. The reactivity of the DA was studied and the properties of DA-based AAMs were compared with both one-part and two-part AAMs activated by solid sodium silicate (NS) and sodium hydroxide/sodium silicate solution (NHNS), respectively. According to results, DA showed reasonable reactivity after heat treatment. DA-based AAMs showed the lowest flowability, but the longest setting time. The strength of NHNS-based AAMs is the highest, followed by DA- and NS-based AAMs. The main reaction product of all types of AAMs is calcium-sodium aluminosilicate hydrate (C-(N)-A-S-H)-type gel. The number of mesopores was greater for both one-part (DA and NS) AAMs than for two-part (NHNS) AAMs. According to cost and emission analyses, DA-based AAMs are cheaper and greener than commercial activator-based AAMs. This study provides a detailed experimental investigation of one-part AAMs activated by an alternative activator to replace the use of commercial alkali silicates.



中文翻译:

热处理废玻璃/ NaOH共混物活化的单份粉煤灰/矿渣基粘合剂的性能:对比研究

研究了在粉煤灰/矿渣的单部分碱活化材料(AAMs)中包含钠钙玻璃粉和氢氧化钠的混合物作为替代的干活化剂(DA)粉。研究了DA的反应性,并将基于DA的AAM与分别由固体硅酸钠(NS)和氢氧化钠/硅酸钠溶液(NHNS)活化的单部分和两部分AAM的性能进行了比较。根据结果​​,DA在热处理后显示出合理的反应性。基于DA的AAM流动性最低,但凝固时间最长。基于NHNS的AAM的强度最高,其次是基于DA和NS的AAM。所有类型的AAM的主要反应产物是钙铝硅酸钠水合物(C-(N)-ASH)型凝胶。一部分(DA和NS)AAM的中孔数量均大于两部分(NHNS)AAM的中孔数量。根据成本和排放分析,基于DA的AAM比基于商业活化剂的AAM更便宜,更环保。这项研究提供了由替代活化剂活化的单组分AAM的详细实验研究,以取代商业化碱金属硅酸盐的使用。

更新日期:2020-05-12
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