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Suspension calcination and alkali leaching of low-grade high-sulfur bauxite: Desulfurization, mineralogical evolution and desilication
International Journal of Minerals, Metallurgy and Materials ( IF 5.6 ) Pub Date : 2020-05-12 , DOI: 10.1007/s12613-019-1941-3
Hong-fei Wu , Jun-qi Li , Chao-yi Chen , Fei-long Xia , Zhen-shan Xie

To enable the utilization of low-grade and high-sulfur bauxite, the suspension calcination was used to remove the sulfur and the activate silica minerals, and the calcinated bauxite was subjected to a desilication process in NaOH solution under atmospheric pressure. The desulfurization and desilication properties and mineralogical evolution were studied by X-ray diffraction, thermogravimetry-differential thermal analysis, scanning electron microscopy, and FactSage methods. The results demonstrate that the suspension calcination method is efficient for sulfur removal: 84.21% of S was removed after calcination at 1000°C for 2 min. During the calcination process, diaspore and pyrite were transferred to α-Al2O3, magnetite, and hematite. The phase transformation of pyrite follows the order FeS2 → Fe3O4 → Fe2O3, and the iron oxides and silica were converted into iron silicate. In the alkali-soluble desilication process, the optimum condition was an alkali solution concentration of 110 g/L, a reaction time of 20 min, and a reaction temperature of 95°C. The corresponding desilication ratio and alumina loss ratio were 44.9% and 2.4%, respectively, and the alumina-to-silica mass ratio of the concentrate was 7.9. The Al2O3·2SiO2, SiO2, and Al2O3 formed during the calcination process could react with NaOH solution, and their activity decreased in the order of Al2O3·2SiO2, SiO2, and Al2O3.



中文翻译:

低品位高硫铝土矿的悬浮煅烧和碱浸:脱硫,矿物演化和脱硅

为了能够利用低品位和高硫铝土矿,悬浮煅烧用于除去硫和活性二氧化硅矿物,并将煅烧的铝土矿在大气压下于NaOH溶液中进行脱硅处理。通过X射线衍射,热重分析,差示热分析,扫描电子显微镜和FactSage方法研究了脱硫和脱硅性能以及矿物学演变。结果表明,悬浮煅烧方法对硫的去除是有效的:在1000°C下煅烧2分钟后,去除了84.21%的S。在煅烧过程期间,硬水铝石和黄铁矿被转移到的α-Al 2 ö 3,磁铁矿和赤铁矿。黄铁矿的相变顺序为FeS 2 →Fe 3 O 4 →Fe 2 O 3,氧化铁和二氧化硅转化为硅酸铁。在碱溶性脱硅过程中,最佳条件是碱溶液浓度为110g / L,反应时间为20min,反应温度为95℃。相应的脱硅率和氧化铝损失率分别为44.9%和2.4%,并且精矿的氧化铝与二氧化硅的质量比为7.9。Al 2 O 3 ·2SiO 2,SiO 2和Al 2 O 3煅烧过程中形成的碳纳米管可与NaOH溶液反应,其活性依次下降为Al 2 O 3 ·2SiO 2,SiO 2和Al 2 O 3

更新日期:2020-05-12
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