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Dependence of Propagation Rate Coefficients in Radical Polymerization on Solution Properties: A Quantitative Thermodynamic Interpretation
Macromolecular Reaction Engineering ( IF 1.8 ) Pub Date : 2020-01-31 , DOI: 10.1002/mren.202000003
Peter Deglmann , Klaus‐Dieter Hungenberg , Hugo M. Vale

Authors want to communicate that there is a typing error in the following sentence in paragraph 4.5:

The largest medium effects of combinatorial origin are expected for systems with either (vS/vM) >> 1, i.e., for large monomers such as iBoMA in small solvents like CO2, or systems with (vS/vM) << 1, i.e., for the smallest monomer ethylene in large solvents like ILs.

should read as follows:

The largest medium effects of combinatorial origin are expected for systems with either (vS/vM) << 1, i.e., for large monomers such as iBoMA in small solvents like CO2, or systems with (vS/vM) >> 1, i.e., for the smallest monomer ethylene in large solvents like ILs.

All presented results remain unchanged and correct; they are not affected by this oversight.



中文翻译:

自由基聚合反应中传播速率系数对溶液性质的依赖性:定量热力学解释

作者想传达的是,第4.5段中的以下句子中有键入错误:

(v S / v M)>> 1的系统(即,在诸如CO 2的小溶剂中的iBoMA之类的大单体)或(v S / v M)< <1,即对于大分子溶剂(如ILs)中的最小单体乙烯。

内容如下:

对于(v S / v M)<< 1的系统,即对于在诸如CO 2的小溶剂中的iBoMA之类的大单体,或(v S / v M)> > 1,即对于大分子溶剂(如ILs)中的最小单体乙烯。

所有给出的结果均保持不变和正确;他们不受此监督的影响。

更新日期:2020-01-31
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