当前位置:
X-MOL 学术
›
Org. Process Res. Dev.
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Correction to “Application of Crabtree/Pfaltz-type Iridium Complexes for the Catalyzed Asymmetric Hydrogenation of an Agrochemical Building Block”
Organic Process Research & Development ( IF 3.1 ) Pub Date : 2020-05-08 , DOI: 10.1021/acs.oprd.0c00206 Jacob Schneekönig , Weiping Liu , Thomas Leischner , Kathrin Junge , Christoph Schotes , Christian Beier , Matthias Beller
Organic Process Research & Development ( IF 3.1 ) Pub Date : 2020-05-08 , DOI: 10.1021/acs.oprd.0c00206 Jacob Schneekönig , Weiping Liu , Thomas Leischner , Kathrin Junge , Christoph Schotes , Christian Beier , Matthias Beller
In Table 2, page 445 of the manuscript, the structures of ligand building blocks 4h and 4f have been drawn incorrectly. The correct structures must beThe reported yields do not change. In Scheme 3, page 446 of the manuscript, the structures of catalysts 5j and 5k have been drawn incorrectly. The correct structures must beThe reported yield does not change. In Table 1, entries 13 and 14, page 444 of the manuscript, the wrong enantiomer of hydrogenation product 2 is given. The correct configuration of 2 must be (R) in both cases. The overall meaning of the manuscript remains unaffected. The Supporting Information has been changed accordingly. The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.oprd.0c00206.
中文翻译:
对“ Crabtree / Pfaltz型铱配合物在农业化学构件的催化不对称加氢中的应用”的更正
在手稿第445页的表2中,配体构件4h和4f的结构绘制不正确。正确的结构必须为。报告的产量不变。在方案446的方案3中,催化剂5j和5k的结构绘制不正确。正确的结构必须是。报告的产率不变。在手稿第444页的表1,条目13和14中,给出了氢化产物2的错误对映异构体。正确配置2必须为(R)。手稿的整体含义不受影响。支持信息已相应更改。可从https://pubs.acs.org/doi/10.1021/acs.oprd.0c00206免费获得支持信息。
更新日期:2020-06-19
- Synthetic procedures; NMR data for TBS-protected pyridyl alcohols, deprotected pyridyl alcohols, and synthesized Ir complexes; HRMS data for the synthesized Ir complexes; results of deuterium experiments; experimental procedures for catalytic tests (PDF)
- Synthetic procedures; NMR data for TBS-protected pyridyl alcohols, deprotected pyridyl alcohols, and synthesized Ir complexes; HRMS data for the synthesized Ir complexes; results of deuterium experiments; experimental procedures for catalytic tests (PDF)
中文翻译:
对“ Crabtree / Pfaltz型铱配合物在农业化学构件的催化不对称加氢中的应用”的更正
在手稿第445页的表2中,配体构件4h和4f的结构绘制不正确。正确的结构必须为。报告的产量不变。在方案446的方案3中,催化剂5j和5k的结构绘制不正确。正确的结构必须是。报告的产率不变。在手稿第444页的表1,条目13和14中,给出了氢化产物2的错误对映异构体。正确配置2必须为(R)。手稿的整体含义不受影响。支持信息已相应更改。可从https://pubs.acs.org/doi/10.1021/acs.oprd.0c00206免费获得支持信息。
- 合成程序;TBS保护的吡啶醇,脱保护的吡啶醇和合成的Ir配合物的NMR数据;合成的Ir配合物的HRMS数据; 氘实验的结果;催化测试的实验程序(PDF)
- 合成程序;TBS保护的吡啶醇,脱保护的吡啶醇和合成的Ir配合物的NMR数据;合成的Ir配合物的HRMS数据; 氘实验的结果;催化测试的实验程序(PDF)