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Correction to “Application of Crabtree/Pfaltz-type Iridium Complexes for the Catalyzed Asymmetric Hydrogenation of an Agrochemical Building Block”
Organic Process Research & Development ( IF 3.1 ) Pub Date : 2020-05-08 , DOI: 10.1021/acs.oprd.0c00206
Jacob Schneekönig , Weiping Liu , Thomas Leischner , Kathrin Junge , Christoph Schotes , Christian Beier , Matthias Beller

In Table 2, page 445 of the manuscript, the structures of ligand building blocks 4h and 4f have been drawn incorrectly. The correct structures must beThe reported yields do not change. In Scheme 3, page 446 of the manuscript, the structures of catalysts 5j and 5k have been drawn incorrectly. The correct structures must beThe reported yield does not change. In Table 1, entries 13 and 14, page 444 of the manuscript, the wrong enantiomer of hydrogenation product 2 is given. The correct configuration of 2 must be (R) in both cases. The overall meaning of the manuscript remains unaffected. The Supporting Information has been changed accordingly. The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.oprd.0c00206.
  • Synthetic procedures; NMR data for TBS-protected pyridyl alcohols, deprotected pyridyl alcohols, and synthesized Ir complexes; HRMS data for the synthesized Ir complexes; results of deuterium experiments; experimental procedures for catalytic tests (PDF)
Synthetic procedures; NMR data for TBS-protected pyridyl alcohols, deprotected pyridyl alcohols, and synthesized Ir complexes; HRMS data for the synthesized Ir complexes; results of deuterium experiments; experimental procedures for catalytic tests (PDF) Electronic Supporting Information files are available without a subscription to ACS Web Editions. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting Information. Files available from the ACS website may be downloaded for personal use only. Users are not otherwise permitted to reproduce, republish, redistribute, or sell any Supporting Information from the ACS website, either in whole or in part, in either machine-readable form or any other form without permission from the American Chemical Society. For permission to reproduce, republish and redistribute this material, requesters must process their own requests via the RightsLink permission system. Information about how to use the RightsLink permission system can be found at http://pubs.acs.org/page/copyright/permissions.html. This article has not yet been cited by other publications. The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.oprd.0c00206.
  • Synthetic procedures; NMR data for TBS-protected pyridyl alcohols, deprotected pyridyl alcohols, and synthesized Ir complexes; HRMS data for the synthesized Ir complexes; results of deuterium experiments; experimental procedures for catalytic tests (PDF)
Synthetic procedures; NMR data for TBS-protected pyridyl alcohols, deprotected pyridyl alcohols, and synthesized Ir complexes; HRMS data for the synthesized Ir complexes; results of deuterium experiments; experimental procedures for catalytic tests (PDF) Electronic Supporting Information files are available without a subscription to ACS Web Editions. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting Information. Files available from the ACS website may be downloaded for personal use only. Users are not otherwise permitted to reproduce, republish, redistribute, or sell any Supporting Information from the ACS website, either in whole or in part, in either machine-readable form or any other form without permission from the American Chemical Society. For permission to reproduce, republish and redistribute this material, requesters must process their own requests via the RightsLink permission system. Information about how to use the RightsLink permission system can be found at http://pubs.acs.org/page/copyright/permissions.html.


中文翻译:

对“ Crabtree / Pfaltz型铱配合物在农业化学构件的催化不对称加氢中的应用”的更正

在手稿第445页的表2中,配体构件4h4f的结构绘制不正确。正确的结构必须为。报告的产量不变。在方案446的方案3中,催化剂5j5k的结构绘制不正确。正确的结构必须是。报告的产率不变。在手稿第444页的表1,条目13和14中,给出了氢化产物2的错误对映异构体。正确配置2必须为(R)。手稿的整体含义不受影响。支持信息已相应更改。可从https://pubs.acs.org/doi/10.1021/acs.oprd.0c00206免费获得支持信息。
  • 合成程序;TBS保护的吡啶醇,脱保护的吡啶醇和合成的Ir配合物的NMR数据;合成的Ir配合物的HRMS数据; 氘实验的结果;催化测试的实验程序(PDF)
合成程序;TBS保护的吡啶醇,脱保护的吡啶醇和合成的Ir配合物的NMR数据;合成的Ir配合物的HRMS数据; 氘实验的结果;催化试验的实验步骤(PDF)无需订阅ACS Web版本即可获得电子支持信息文件。美国化学学会在任何可版权保护的支持信息中拥有版权权益。ACS网站上提供的文件只能下载供个人使用。未经美国化学学会的许可,不得以其他方式允许用户以机器可读形式或任何其他形式全部或部分复制,重新发布,重新分发或出售ACS网站上的任何支持信息。为了获得复制许可,重新发布并重新分发此材料,请求者必须通过RightsLink许可系统处理自己的请求。有关如何使用RightsLink权限系统的信息,请访问http://pubs.acs.org/page/copyright/permissions.html。本文尚未被其他出版物引用。可从https://pubs.acs.org/doi/10.1021/acs.oprd.0c00206免费获得支持信息。
  • 合成程序;TBS保护的吡啶醇,脱保护的吡啶醇和合成的Ir配合物的NMR数据;合成的Ir配合物的HRMS数据; 氘实验的结果;催化测试的实验程序(PDF)
合成程序;TBS保护的吡啶醇,脱保护的吡啶醇和合成的Ir配合物的NMR数据;合成的Ir配合物的HRMS数据; 氘实验的结果;催化试验的实验步骤(PDF)无需订阅ACS Web版本即可获得电子支持信息文件。美国化学学会在任何可版权保护的支持信息中拥有版权权益。ACS网站上提供的文件只能下载供个人使用。未经美国化学学会的许可,不得以其他方式允许用户以机器可读形式或任何其他形式全部或部分复制,重新发布,重新分发或出售ACS网站上的任何支持信息。为了获得复制许可,重新发布并重新分发此材料,请求者必须通过RightsLink许可系统处理自己的请求。有关如何使用RightsLink权限系统的信息,请访问http://pubs.acs.org/page/copyright/permissions.html。
更新日期:2020-06-19
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