The copper(I)‐catalyzed triazole formation from azides and terminal alkynes has received the benchmark of “click chemistry” because of its dependability and explicitness. The extensive utility of click chemistry in all aspects from making classical phosphine ligands, investigating its reactivity in serving as an effective catalyst for various organic transformations is well documented. Therefore, designing a decent ligand system with adequate nature and vast diversity is vital for having to deal with the demanding substrates in this area. Due to the benefits of broad functional group tolerance and the use of stable reagents, the Pd‐catalyzed organic transformations are most valuable in fine chemical synthesis and drug industry. The present review focuses mainly on the synthesis of a novel class of triazole based phosphines and their complexation behavior with palladium and catalytic applications.

中文翻译：

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三唑类附加膦：合成，钯配合物和催化研究

由叠氮化物和末端炔烃形成的铜（I）催化的三唑形成因其可靠性和明确性而获得了“点击化学”的基准。点击化学在制备经典膦配体，研究其作为各种有机转化的有效催化剂的反应性方面的各个方面都具有广泛的用途。因此，设计具有适当性质和广泛多样性的体面配体系统对于必须处理该领域中苛刻的底物至关重要。由于宽泛的官能团耐受性和使用稳定的试剂的好处，Pd催化的有机转化在精细化学合成和制药行业中最有价值。