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Facile C–S Bond Cleavage of Aryl Sulfoxides Promoted by Brønsted Acid
Synlett ( IF 1.7 ) Pub Date : 2020-05-06 , DOI: 10.1055/s-0040-1707109 Nuno Maulide , Bogdan R. Brutiu , Immo Klose
Synlett ( IF 1.7 ) Pub Date : 2020-05-06 , DOI: 10.1055/s-0040-1707109 Nuno Maulide , Bogdan R. Brutiu , Immo Klose
A method for the Bronsted acid promoted desulfination of aryl sulfoxides is presented. In the presence of a thiol, electron-rich sulfoxides undergo C–S bond cleavage to give the corresponding protodesulfinated arenes and disulfides.
中文翻译:
布朗斯台德酸促进芳基亚砜的 C-S 键裂解
提出了一种布朗斯台德酸促进芳基亚砜脱硫的方法。在硫醇存在下,富含电子的亚砜会发生 C-S 键断裂,得到相应的原脱硫芳烃和二硫化物。
更新日期:2020-05-06
中文翻译:
布朗斯台德酸促进芳基亚砜的 C-S 键裂解
提出了一种布朗斯台德酸促进芳基亚砜脱硫的方法。在硫醇存在下,富含电子的亚砜会发生 C-S 键断裂,得到相应的原脱硫芳烃和二硫化物。