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Remarkable efficiency of Ni supported on hydrothermally synthesized CeO2 nanorods for low-temperature CO2 hydrogenation to methane
Catalysis Communications ( IF 3.4 ) Pub Date : 2020-05-07 , DOI: 10.1016/j.catcom.2020.106036
Georgios Varvoutis , Maria Lykaki , Sofia Stefa , Eleni Papista , Sónia A.C. Carabineiro , Georgios E. Marnellos , Michalis Konsolakis

Nickel particles deposited on hydrothermally synthesized ceria nanorods (CeO2-NR) were found to be highly active and stable for CO2 methanation. A CO2-to-CH4 yield of 92% was achieved at 300 °C. The impact of various operational parameters was explored in conjunction with a thermodynamic analysis. The superior performance of Ni/CeO2-NR was demonstrated through a comparison with i) CeO2 and Ni/CeO2 commercial products, ii) various M/CeO2-NR lab-synthesized catalysts (M = Cu, Co, Fe), and iii) state-of-the-art literature catalysts. The results revealed that a unique combination of Ni with ceria nanorods is required for boosting the reducibility and in turn the methanation efficiency.



中文翻译:

水热合成的CeO 2纳米棒上负载的Ni对低温CO 2氢化成甲烷的显着效率

发现沉积在水热合成的二氧化铈纳米棒(CeO 2 -NR)上的镍颗粒对CO 2甲烷化具有很高的活性和稳定性。在300℃下获得了92%的CO 2 -CH 4产率。结合热力学分析探讨了各种操作参数的影响。通过与i)CeO 2和Ni / CeO 2商业产品,ii)各种M / CeO 2的比较证明了Ni / CeO 2 -NR的优越性能。-NR实验室合成的催化剂(M = Cu,Co,Fe),和iii)最新文献催化剂。结果表明,Ni与二氧化铈纳米棒的独特结合是提高还原度和甲烷化效率所必需的。

更新日期:2020-05-07
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