A system consisting of hydrogen peroxide/persulfate (H₂O₂/S₂O₈²⁻) catalyzed by siderite was attempted to oxidize nine representative petroleum hydrocarbon compounds [benzene, toluene, ethylbenzene, m-xylene, p-xylene, o-xylene, 1,2,4-trimethylbenzene, methyl-tert-butyl ether, and naphthalene] that tend to persist in the environment. Oxidation under different siderite dosages, H₂O₂:S₂O₈²⁻ ratios, and pH conditions were investigated. Results indicated that oxidation rates increased from 1.21–4.62 to 1.77–8.94 d⁻¹ as siderite increased from 0.16 to 0.48 g/40 mL (H₂O₂:Na₂S₂O₈ = 5:1, initial pH = 3.0), except for naphthalene (decreased from 0.58 to 0.45 d⁻¹ with increased siderite dosage). When the H₂O₂:S₂O₈²⁻ ratio was increased from 1:1 to 5:1 (siderite = 0.16 g, initial pH = 3.0), the oxidation rates increased from 0.02–0.73 to 0.33–2.19 d⁻¹. However, as pH increased to > 5.5 (siderite = 0.16 g, H₂O₂:Na₂S₂O₈ = 2.5:1), the oxidation rates of petroleum hydrocarbons decreased to 0.003–0.09 d⁻¹, which was approximately 90% less than that at pH = 3.0. The partial correlations and principal component analysis of the experimental data were conducted. Overall, both siderite dosage and H₂O₂:S₂O₈²⁻ ratio correlated positively with oxidation efficiency. The oxidation potential by H₂O₂/S₂O₈²⁻ mixtures towards the target petroleum hydrocarbon compounds seemed to be more sensitive to pH conditions than to siderite dosages or H₂O₂:S₂O₈²⁻ ratios.

尝试由菱铁矿催化的由过氧化氢/过硫酸盐（H ₂ O ₂ / S ₂ O ₈ ^2-）组成的系统氧化九种代表性的石油烃化合物[苯，甲苯，乙苯，间二甲苯，对二甲苯，邻二甲苯二甲苯，1,2,4-三甲基苯，甲基叔丁基醚和萘]倾向于在环境中持续存在。研究了在不同菱铁矿剂量，H ₂ O ₂：S ₂ O ₈ ^2-的比例和pH条件下的氧化。结果表明，氧化速度从1.21–4.62增加到1.77–8.94 d ^-1，而菱铁矿从0.16增加到0.48 g / 40 mL（H ₂O ₂：Na ₂ S ₂ O ₈  = 5：1，初始pH = 3.0），但萘除外（随着菱铁矿用量的增加，从0.58降至0.45 d ^-1）。当H ₂ ö ₂：S ₂ ö ₈ ^2-比从1：1增加到5：1（菱铁矿= 0.16克，初始pH = 3.0）时，氧化速率从0.02-0.73增加到0.33-2.19 d ^{- 1}。但是，随着pH值增加到> 5.5（菱铁矿= 0.16 g，H ₂ O ₂：Na ₂ S ₂ O ₈  = 2.5：1），石油碳氢化合物的氧化速率下降到0.003-0.09 d^-1，比pH = 3.0时约低90％。进行了实验数据的偏相关和主成分分析。总体而言，菱铁矿用量和H ₂ O ₂：S ₂ O ₈ ^2-的比例均与氧化效率呈正相关。H ₂ O ₂ / S ₂ O ₈ ^2-混合物对目标石油烃化合物的氧化电位似乎对pH条件比菱铁矿剂量或H ₂ O ₂：S ₂ O ₈ ^2-的比例更敏感。