A solvothermal method was used to synthesize MIL-101(Fe) and MIL-88(Fe), which were used for alkylation of benzene. The synthesized catalysts were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, field emission scanning electron microscope, dynamic light scattering, and BET techniques. Metal-organic frameworks (MOFs) were modeled to investigate the catalytic performance and existence of mass transfer limitations. Calculated effectiveness factors revealed absence of internal and external mass transfer. Sensitivity analysis revealed best operating conditions over MIL-101 at 120°C and 5 bar and over MIL-88 at 142°C and 9 bar.

溶剂热法用于合成MIL-101（Fe）和MIL-88（Fe），用于苯的烷基化。通过X射线衍射，傅里叶变换红外光谱，场发射扫描电子显微镜，动态光散射和BET技术对合成的催化剂进行了表征。对金属有机骨架（MOF）进行建模，以研究其催化性能和传质限制的存在。计算出的有效性因子表明没有内部和外部传质。灵敏度分析显示，在120°C和5 bar的条件下超过MIL-101的最佳工作条件，在142°C和9 bar的条件下超过MIL-88的最好工作条件。