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Microwave dielectric properties of (1-x)Ba(Mg1/3Ta2/3) O3 – (x)Ba(Mg1/8Ta3/4)O3 ceramics synthesized by one pot metathesis process
Ferroelectrics ( IF 0.8 ) Pub Date : 2020-05-04
Yogita Bisht, Pullanchiyodan Abhilash, Deepa Rajendran Lekshmi, M. Thirumal

Complex perovskites (1-x)Ba(Mg1/3Ta2/3)O3 – (x)Ba(Mg1/8Ta3/4)O3 (0 ≤ x ≤ 1) were investigated for possible solid solution and composite range using one pot metathesis process. This process lowers the synthesis temperature of Ba-Mg-Ta ceramics to just 1100 °C. Till x = 0.5 the powder X-ray pattern shows the presence of only Ba(Mg1/3Ta2/3)O3 phase. Above x = 0.5 both Ba(Mg1/3Ta2/3)O3 and Ba(Mg1/8Ta3/4)O3 phase starts crystallizing. The samples can be sintered to >90% density at around 1350 °C. Dielectric properties measured at GHz frequency exhibits values in the range: εr = 22 − 29, Q.f = 7000 − 36000 GHz and τf = 14 − 50 ppm/ °C.



中文翻译:

一锅复分解法合成(1-x)Ba(Mg1 / 3Ta2 / 3)O3-(x)Ba(Mg1 / 8Ta3 / 4)O3陶瓷的微波介电性能

研究了复合钙钛矿(1-x)Ba(Mg 1/3 Ta 2/3)O 3-(x)Ba(Mg 1/8 Ta 3/4)O 3(0≤x≤1)和一个锅复分解过程的合成范围。此过程将Ba-Mg-Ta陶瓷的合成温度降低到1100°C。直到x = 0.5,粉末X射线图显示仅存在Ba(Mg 1/3 Ta 2/3)O 3相。x = 0.5以上的Ba(Mg 1/3 Ta 2/3)O 3和Ba(Mg 1/8 Ta 3/4)O 3相开始结晶。可以在约1350°C的温度下将样品烧结至> 90%的密度。在GHz频率下测得的介电性能的范围为:εr = 22-29 Qf = 7000-36000 GHz和τf = 14-50 ppm /°C。

更新日期:2020-05-04
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