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Interfacial engineering revolutionizers: perovskite nanocrystals and quantum dots accentuated performance enhancement in perovskite solar cells
Critical Reviews in Solid State and Materials Sciences ( IF 10.8 ) Pub Date : 2020-05-03
Shaan Bibi Jaffri, Khuram Shahzad Ahmad

Utilization of efficient nanomaterials in perovskite solar cells (PSCs) for effectual conversion of solar energy to electrical energy has prompted the extensive progression of PSCs as a suitable alternative to silicon-based photovoltaic (PV) technologies. Most recent progressions are inclusive of nanoscale materials incorporation particularly nanocrystals (NCs) and quantum dots (QDs) with unique sizes, morphological and compositional aspects aimed at PSCs modification. In all conventional architectures of the PSCs, there are number of interfaces between the transport layers and active absorber perovskite layer. Nanocrystals and quantum dots have been employed for the interfacial engineering in PSCs owing to their remarkable optoelectronic and photo-physical characteristics favoring the facile and efficient power generation and reducing dependence on silicone-based PVs. Myriad of NCs and QDs having inorganic and/or inorganic perovskite composition have been investigated, however, the overall synthetic costs, procedural complications, current, and voltage (J–V) hysterical response and stability toward air and light needs further meticulous investigations due to which PV community has been disseminating experimental results rapidly since last few years. Considering the potential of perovskite NCs and QDs, current review has for the first time explored the most recent progressions done in utilization of these nanoscale materials in augmenting PSCs PV functionality through interface modification. Magnifying extent of nanoscale materials for PSCs modification and current investigation signifies the future candidacy of perovskite NCs and QDs as humanity gallants for provisioning of cheaper and sustainable power sources.



中文翻译:

界面工程革命者:钙钛矿纳米晶体和量子点增强了钙钛矿太阳能电池的性能增强

钙钛矿太阳能电池(PSC)中有效纳米材料的有效利用将太阳能转化为电能已促使PSC广泛发展,成为硅基光伏(PV)技术的合适替代品。最新进展包括纳米级材料的结合,特别是纳米晶体(NCs)和量子点(QDs),其具有针对PSC修饰的独特尺寸,形态和组成方面。在PSC的所有常规体系结构中,在传输层和活性吸收体钙钛矿层之间存在许多界面。纳米晶体和量子点已被用于PSC的界面工程中,这是因为它们具有显着的光电和光物理特性,有利于简便高效地发电,并减少了对硅基PV的依赖。已经研究了无数具有无机和/或无机钙钛矿成分的NC和QD,但是,由于以下原因,总体合成成本,程序复杂性,电流和电压(J–V)滞后响应以及对空气和光的稳定性需要进一步的仔细研究。自最近几年以来,哪个PV社区一直在迅速传播实验结果。考虑到钙钛矿NC和QD的潜力,本篇综述首次探讨了利用这些纳米级材料通过界面修饰增强PSCs PV功能的最新进展。用于PSC改性的纳米级材料的放大程度以及当前的研究表明,钙钛矿型NC和QD有望成为人类提供廉价和可持续电源的勇士。

更新日期:2020-05-03
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