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Effect of short jute fibers on the hydrolytic degradation behavior of poly(lactic acid)
Polymer Degradation and Stability ( IF 6.3 ) Pub Date : 2020-05-04 , DOI: 10.1016/j.polymdegradstab.2020.109214
Ning Jiang , Yaomin Li , Yuankun Li , Tao Yu , Yan Li , Di Li , Jiachuan Xu , Cuiping Wang , Ying Shi

This paper investigates the effect of short jute fibers on the hydrolysis of poly (lactic acid) (PLA) in deionized water at 50 and 60 °C. The water absorption, thermal and mechanical properties (tensile and flexural), morphological structure, as well as molecular weight of jute/PLA composites and PLA were evaluated before and after aging. The results showed that the jute/PLA composites had higher water absorption but approximately equal mechanical properties compared with PLA. This indicates that it is a feasible way to reinforce PLA by adding short jute fibers. Both PLA and jute/PLA composites undergo hydrolysis after aging. Further analysis revealed that as the vibration and mobility of PLA molecular chains were hindered by addition of jute fibers, jute/PLA composites had a slower decline in mechanical properties than PLA, and thus showed a slower hydrolysis. Moreover, the addition of jute fibers resulted in mechanical interlocking, which in turn increased the load carrying capability of jute/PLA composites.



中文翻译:

黄麻短纤维对聚乳酸水解降解行为的影响

本文研究短黄麻纤维在50和60°C的去离子水中对聚乳酸(PLA)水解的影响。在老化之前和之后,评估了黄麻/ PLA复合材料和PLA的吸水率,热和机械性能(拉伸和弯曲),形态结构以及分子量。结果表明,与PLA相比,黄麻/ PLA复合材料具有更高的吸水率,但力学性能几乎相同。这表明通过添加短的黄麻纤维来增强PLA是一种可行的方法。PLA和黄麻/ PLA复合材料在老化后都会发生水解。进一步的分析表明,由于加入黄麻纤维会阻碍PLA分子链的振动和迁移,因此黄麻/ PLA复合材料的机械性能下降速度要比PLA慢,因此显示出较慢的水解。此外,黄麻纤维的添加导致机械互锁,进而提高了黄麻/ PLA复合材料的承载能力。

更新日期:2020-05-04
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