Studies of the growth of large-area free-standing single-crystalline films of p-quinquephenyl are presented. High-quality crystals were grown by slow cooling of a hot chlorobenzene solution. Worse quality large-area free-standing single crystals of p-quinquephenyl were also grown by using physical vapor transport and used for comparison. The crystal structure of p-quinquephenyl at 293 K and 85 K was refined by single-crystal X-ray diffraction. The optical absorption and photoluminescence spectra of solutions and crystalline films were obtained and analyzed; a positive solvatochromic effect was detected.

中文翻译：

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对喹啉苯基的大面积自由站立单晶膜：生长，结构和光致发光性能。

提出了对-对五苯基的大面积独立式单晶膜的生长研究。通过缓慢冷却热的氯苯溶液来生长高质量的晶体。使用物理气相传输法还生长了质量较差的大面积对喹啉苯基单晶，并将其用于比较。通过单晶X射线衍射对在293 K和85 K处的对喹啉苯基的晶体结构进行精制。获得并分析了溶液和结晶膜的光吸收和光致发光光谱。检测到正的溶剂化变色作用。