Ca‐α‐SiAlON:Eu²⁺ oxynitride phosphors are typical luminescent materials with high thermal tolerances. A series of zinc borophosphate glass samples (ZnO–B₂O₃–P₂O₅) were prepared to investigate their ability to disperse Ca‐α‐SiAlON:Eu²⁺ phosphor powders and to obtain phosphor‐in‐glass (PiG). PiG was prepared with SiAlON and zinc borophosphate glass through a melting process, and seven types of PiGs were successfully obtained without obvious degradation of SiAlON. In particular, PiGs prepared from 30ZnO–40B₂O₃–30P₂O₅ and 60ZnO–30B₂O₃–10P₂O₅ (mol%) glasses showed the highest quantum efficiency (QE). The glass structures of the mother glasses were investigated by nuclear magnetic resonance spectroscopy (NMR) and Raman spectroscopy; it was important to reduce the Q⁰ species of PO₄ units and 4‐coordinate boron for a high QE. From the X‐ray diffraction (XRD) and scanning electron microscopy (SEM) images, it was established that ZnAl₂O₄ was formed around the SiAlON powders in PiG composed of the 60ZnO–30B₂O₃–10P₂O₅ (mol%) glass.

中文翻译：

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硼硅酸锌玻璃作为SiAlON荧光粉分散介质的探索

Ca-SiAlON：Eu ²⁺氮氧化物荧光粉是具有高耐热性的典型发光材料。准备了一系列硼硼酸锌玻璃样品（ZnO–B ₂ O ₃ –P ₂ O ₅），以研究其分散Ca-α-SiAlON：Eu ²⁺荧光粉的能力并获得玻璃中荧光粉（PiG） 。用熔化的SiAlON和硼磷酸锌玻璃制备PiG，成功地获得了七种类型的PiG，而SiAlON没有明显的降解。特别是由30ZnO–40B ₂ O ₃ –30P ₂ O ₅和60ZnO–30B ₂ O ₃制备的PiG。–10P ₂ O ₅（mol％）玻璃显示出最高的量子效率（QE）。通过核磁共振波谱（NMR）和拉曼光谱研究了母玻璃的玻璃结构。对于高QE ，减少PO ₄单元和4坐标硼的Q ⁰物种非常重要。从X射线衍射（XRD）和扫描电子显微镜（SEM）图像，可以确定在由60ZnO–30B ₂ O ₃ –10P ₂ O ₅（mol）组成的PiG中，SiAlON粉末周围形成了ZnAl ₂ O _4。％）玻璃。