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Selenium-directed synthesis of Pd nanoparticles on mesoporous silica-coated Fe3O4: An efficient magnetic catalyst for oxidative alkene cracking
Catalysis Communications ( IF 3.7 ) Pub Date : 2020-04-29 , DOI: 10.1016/j.catcom.2020.106031
Zhida Zhu , Wenjun Wang , Li Zeng , Fan Zhang , Jingjing Liu

By using selenium-directing technology, magnetic mesoporous silica-supported nano palladium catalyst (Pd/SiO2/Fe3O4-Se) for oxidative alkene cracking reactions could be synthesized in a relatively concise method. During the materials calcination process, decomposition and sublimation of selenium moieties of selenized Fe3O4 core could direct the formation of the micro-structures of nano materials more orderly, endowing the material overwhelmingly higher catalytic activity than the similar material prepared from unselenized Fe3O4. As the first report of synthesizing magnetic materials via the selenium-directing method, this work is of both science and application meanings and may inspire new ideas for the development of related novel materials.



中文翻译:

介孔二氧化硅包覆的Fe 3 O 4的硒定向合成Pd纳米粒子:氧化烯烃裂解的有效磁性催化剂

通过使用硒引导技术,可以用相对简洁的方法合成磁性介孔二氧化硅负载的纳米钯催化剂(Pd / SiO 2 / Fe 3 O 4 -Se),用于氧化烯烃的裂解反应。在材料煅烧过程中,硒化Fe 3 O 4核的硒部分的分解和升华可以更直接地指导纳米材料的微观结构的形成,与未硒化Fe 3制备的相似材料相比,该材料具有更高的催化活性。Ø 4。作为通过硒定向法合成磁性材料的第一篇报道,这项工作具有科学和应用意义,并可能为相关新型材料的开发启发新的思路。

更新日期:2020-04-29
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