Fullerenes with extended π-systems are idea building blocks to construct various supramolecular assemblies and functional micro/nanostructures. Researches on fullerenes micro/nanostructures (FMNSs) have grown rapidly in the field of energy-related applications during recent years because of their unique spherical molecular structures and tunable architectures at the molecular level using solution-based techniques. Accordingly, rational design and fabrication of fullerene-based electrode materials with excellent electrochemical performances can be achieved in solution by pore fabrication, heteroatom doping, co-assembly with other moieties, and so on. In this Review, we summarize the state-of-the-art progresses on the controlled synthesis of FMNSs with a particular emphasis on their energy applications. First, we introduce the recent advances on FMNSs with various structural dimensions, including the micro/nanostructures of different fullerene forms (empty fullerenes, metallofullerenes, and fullerene co-assemblies with other moieties, such as graphene, carbon nanotubes, and porphyrins). We also discuss in detail the utilization of these FMNS materials in supercapacitors and electrocatalysis. Finally, the challenges and opportunities for the rational design and future application of FMNSs are summarized and highlighted.

具有扩展的π系统的富勒烯是构筑各种超分子组装体和功能性微/纳米结构的思想构建块。近年来，由于富勒烯微/纳米结构（FMNS）的独特球形分子结构和使用基于溶液的技术在分子水平上的可调结构，因此在能源相关应用领域的研究发展迅速。因此，通过孔制造，杂原子掺杂，与其他部分的共组装等，可以在溶液中实现具有优异的电化学性能的富勒烯基电极材料的合理设计和制造。在这篇综述中，我们总结了FMNSs受控合成的最新进展，特别强调了它们的能源应用。第一，我们介绍了具有各种结构尺寸的FMNS的最新进展，包括不同富勒烯形式（空富勒烯，金属富勒烯以及与其他部分（例如石墨烯，碳纳米管和卟啉）的富勒烯共组装体）的微/纳米结构。我们还将详细讨论这些FMNS材料在超级电容器和电催化中的利用。最后，总结并强调了FMNS的合理设计和未来应用所面临的挑战和机遇。我们还将详细讨论这些FMNS材料在超级电容器和电催化中的利用。最后，总结并强调了FMNS的合理设计和未来应用所面临的挑战和机遇。我们还将详细讨论这些FMNS材料在超级电容器和电催化中的利用。最后，总结并强调了FMNS的合理设计和未来应用所面临的挑战和机遇。