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One-dimensional magnet basic copper(ii) dihydroxoborate Cu2{BO(OH)2}(OH)3: synthesis and properties
Russian Chemical Bulletin ( IF 1.7 ) Pub Date : 2020-04-01 , DOI: 10.1007/s11172-020-2821-8
A. A. Vorobyova , A. I. Shilov , F. M. Spiridonov , A. V. Knotko , I. L. Danilovich , A. N. Vasiliev , I. V. Morozov

Basic copper(ii) dihydroxoborate Cu2{BO(OH)2}(OH)3 contains infinite chains consisting of [CuO4] squares that are linked together by sharing opposite edges, due to which this compound is interesting in terms of low-dimensional magnetism. However, investigations of its physical properties are hindered by difficulties with the preparation of single-phase samples. The synthesis method was optimized, and the factors affecting the formation of a crystalline product were established. The synthesized compound was characterized by X-ray diffraction and IR spectroscopy, and its thermal stability was studied. The crystallite formation from the initially unstructured precipitate is described using scanning electron microscopy. An investigation of the temperature dependence of magnetic susceptibility showed that the magnetic properties of basic copper(ii) borate are well described by the weakly alternating spin-1/2 Heisenberg chain model.

中文翻译:

一维磁体碱性铜(ii)二氢硼酸Cu2{BO(OH)2}(OH)3:合成与性能

碱性二氢硼酸铜 (ii) Cu2{BO(OH)2}(OH)3 包含由 [CuO4] 方块组成的无限链,这些方块通过共享对边连接在一起,因此该化合物在低维磁性方面很有趣. 然而,单相样品的制备困难阻碍了对其物理性质的研究。优化了合成方法,确定了影响结晶产物形成的因素。合成的化合物通过X射线衍射和红外光谱表征,并研究了其热稳定性。使用扫描电子显微镜描述了从最初的非结构化沉淀物形成的微晶。
更新日期:2020-04-01
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