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Modification of a rice husk-based activated carbon by thermal treatment and its effect on its electrochemical performance as a supercapacitor electrode
New Carbon Materials ( IF 5.7 ) Pub Date : 2019-10-04 , DOI: 10.1016/s1872-5805(19)30021-6
Cheng-yuan Xiao , Wen-li Zhang , Hai-bo Lin , Yong-xia Tian , Xin-xin Li , Yi-ye Tian , Hai-yan Lu

A hierarchically porous rice husk-based activated carbon, which had been prepared by a combined method (carbonization, NaOH-leaching and KOH activation), has a high specific capacitance and power density as a supercapacitor electrode in aqueous or organic electrolytes. It was subjected to a simple thermal treatment at 800 °C for 1 h to modify its microstructure and electrochemical performance. Results indicate that its original hierarchical pore structure is retained and the number of oxygen-containing functional groups is reduced after this modification. Mesopores developed and the volume ratio of mesopores to total pores increased from 25.62 to 33.62%. The modified activated carbon showed a higher specific capacitance of 147 F g−1 than the unmodified one (116 F g−1) at a current density of 0.5 A g−1. The voltage of the modified activated carbon was 84.5% of its initial value after self-discharge for 24 h, which is higher than that (75.2%) of the unmodified one. The capacitance retention of the modified carbon was 92% while that of the unmodified one was 85% after 10 000 galvanostatic charge/discharge cycles at 1 A g−1, indicating the better cycling stability of the former.



中文翻译:

稻壳基活性炭的热处理改性及其对超级电容器电极电化学性能的影响

通过组合方法(碳化,NaOH浸出和KOH活化)制备的分层多孔的稻壳基活性炭具有高比电容和功率密度,可作为水性或有机电解质中的超级电容器电极。在800°C下对其进行简单的热处理1 h,以改变其微观结构和电化学性能。结果表明,经过这种修饰后,其原始的分层孔结构得以保留,含氧官能团的数量减少了。产生了中孔,中孔与总孔的体积比从25.62%增加到33.62%。改性的活性炭比未改性的活性炭具有更高的比电容147 F g -1(116 F g -1)在0.5 A g -1的电流密度下。自放电24小时后,改性活性炭的电压为其初始值的84.5%,高于未改性活性炭的电压(75.2%)。在1 A g -1下进行10000次恒电流充电/放电循环后,改性碳的电容保持率为92%,而未改性碳的电容保持率为85%,表明前者具有更好的循环稳定性。

更新日期:2019-10-04
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