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Preparation, characterization, and tribological properties of silica-nanoparticle-reinforced B-N-co-doped reduced graphene oxide as a multifunctional additive for enhanced lubrication
Friction ( IF 6.3 ) Pub Date : 2020-04-25 , DOI: 10.1007/s40544-019-0331-1
Sang Xiong , Baosen Zhang , Shuai Luo , Hao Wu , Zhen Zhang

Microwave-synthesized SiO2-reinforced B-N-co-doped reduced graphene oxide (SiO2-B-N-GO) nanocomposites were characterized by X-ray photon spectroscopy (XPS), X-ray diffraction (XRD), infrared (IR) spectroscopy, and transmission electron microscopy/energy dispersive X-ray (TEM/EDX) analysis. The tribological properties of the SiO2-B-N-GO prepared as anti-wear additives for enhanced lubrication were studied using a four-ball tester. The experiment results indicated that SiO2-B-N-GO exhibits excellent load-carrying, anti-wear, and anti-friction properties in a base oil, especially at the optimal concentration of additives at 0.15 wt%. The wear scar diameter decreased from 0.70 to 0.37 mm and the coefficient of friction was reduced from 0.092 to 0.070, which reductions are attributed to the formation of B-N and graphene layer tribofilms of several tens of nanometers in thickness that prevented direct contact between metals.



中文翻译:

二氧化硅-纳米粒子增强的BN-共掺杂的还原氧化石墨烯作为增强润滑的多功能添加剂的制备,表征和摩擦学性能

微波合成的SiO 2增强的BN共掺杂的还原氧化石墨烯(SiO 2 -BN-GO)纳米复合材料的特征在于X射线光子光谱(XPS),X射线衍射(XRD),红外(IR)光谱,以及透射电子显微镜/能量色散X射线(TEM / EDX)分析。使用四球测试仪研究了用作增强润滑的抗磨添加剂SiO 2 -BN-GO的摩擦学性能。实验结果表明SiO 2-BN-GO在基础油中表现出优异的负载,抗磨和抗磨性能,尤其是在添加剂的最佳浓度为0.15 wt%时。磨痕直径从0.70降低到0.37 mm,摩擦系数从0.092降低到0.070,其减少归因于形成BN和数十纳米厚的石墨烯层摩擦膜,从而阻止了金属之间的直接接触。

更新日期:2020-04-25
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