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Structural and morphological properties of β-Ga2O3 nanostructures synthesized at various deposition temperatures
Physica E: Low-dimensional Systems and Nanostructures ( IF 2.9 ) Pub Date : 2020-04-25 , DOI: 10.1016/j.physe.2020.114153
P.R. Jubu , F.K. Yam , Khaled M. Chahrour

Gallium oxide (Ga2O3) nanostructures (NSs) are grown on Si substrate via vapor-solid (VS) mechanism by the carbon-hydrogen reduction of gallium oxide powder in chemical vapor deposition (CVD) system. The NSs are synthesized at different deposition temperatures of 850–1150 °C with the apparent activation energy of 120.98 kJ/mol(1.24 eV/atom). The crystalline monoclinic phase is confirmed by high-resolution X-ray diffraction (HR-XRD). Field-emission scanning electron microscopy (FE-SEM) revealed that morphology of β-Ga2O3 NSs comprises of nanoworms and nanowires. The Williamson-Hall (W–H) and Scherrer method are used to evaluate the size of crystallites and strain in the β-Ga2O3 NSs. Crystallite size is observed to increase with deposition temperature as the crystallinity of the films improved. Physical parameters such as strain, root-mean-square strain, dislocation density and texture coefficient values are calculated from the XRD results. Elemental composition investigated by energy dispersive X-ray (EDX) reveal strong peaks of Ga and O without impurities. The photodetection behavior of the material demonstrates remarkable response to 365 nm (2.09 mW/cm2) light.



中文翻译:

结构和形态性质的β-Ga 2个ö 3纳米结构在各种沉积温度下合成

在化学气相沉积(CVD)系统中,通过氧化镓粉末的碳氢还原,通过汽固(VS)机理在硅衬底上生长了氧化镓(Ga 2 O 3)纳米结构(NSs)。NSs是在850-1150°C的不同沉积温度下合成的,其表观活化能为120.98 kJ / mol(1.24 eV /原子)。结晶单斜晶相通过高分辨率X射线衍射(HR-XRD)确认。场发射扫描电子显微镜(FE-SEM)揭示的β-Ga的其形态2 ö 3奈米包括纳米蠕虫和纳米线。威廉逊-霍尔(W-H)和谢乐法用于评估微晶的在大小和应变的β-Ga 2 ö 3NSs。随着膜的结晶度提高,观察到微晶尺寸随沉积温度而增加。物理参数,如应变,均方根应变,位错密度和织构系数值均根据XRD结果计算得出。通过能量色散X射线(EDX)研究的元素组成显示出Ga和O的强峰,而没有杂质。该材料的光电检测行为显示出对365 nm(2.09 mW / cm 2)光的显着响应。

更新日期:2020-04-25
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