Flavin doesn't put all oxygens in one basket.,Nature Chemical Biology

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Flavin doesn't put all oxygens in one basket.
Nature Chemical Biology ( IF 12.9 ) Pub Date : 2020-05-01 , DOI: 10.1038/s41589-020-0523-z
David Leys ₁ , Nigel S Scrutton ₁

Affiliation

Oxygen activation mechanisms catalyzed by flavin cofactors are established for electron transfer (oxidases) and C4a covalent flavin–oxygen adduct formation (oxygen-inserting monooxygenases). A new paradigm for oxygen insertion involving a flavin-N5-aminoperoxide intermediate has now been discovered in select flavin-dependent monooxygenases.

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