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Efficient photocatalytic synthesis of l -glutamate using a self-assembled carbon nitride/sulfur/porphyrin catalyst
Environmental Chemistry Letters ( IF 15.0 ) Pub Date : 2020-04-20 , DOI: 10.1007/s10311-020-01004-x
Surabhi Chaubey , Chandani Singh , Pooja Singh , Abhishek Kumar , P. P. Pande , Jin-Ook Baeg , D. K. Dwivedi , Rajesh K. Yadav

Mimicking natural photosynthesis is a promising way to produce fine chemicals, yet there is a need for efficient catalysts. Here, we synthesized a photocatalyst made of self-assembled graphitic carbon nitride/sulfur/cobalt (III) tetraphenyl porphyrin, and we used this photocatalyst for production of the l-glutamate amino acid in 93.6% yield. Regeneration of the 1,4-dihydronicotinamide adenine dinucleotide cofactor under visible light reached 88.3%.



中文翻译:

使用自组装氮化碳/硫/卟啉催化剂高效光催化合成谷氨酸

模仿自然光合作用是生产精细化学品的一种有前途的方法,但是仍然需要有效的催化剂。在此,我们合成了由自组装石墨碳氮化物/硫/钴(III)四苯基卟啉制成的光催化剂,并使用该光催化剂以93.6%的产率生产了1-谷氨酸氨基酸。在可见光下1,4-二氢烟酰胺酰胺腺嘌呤二核苷酸辅因子的再生达到88.3%。

更新日期:2020-04-21
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