Enzymatic biofuel cells (EBFCs) have attracted increasing attention due to their potential to harvest energy from a wide range of fuels under mild conditions. Fabrication of effective bioelectrodes is essential for the practical application of EBFCs. Graphene possesses unique physiochemical properties making it an attractive material for the construction of EBFCs. Despite these promising properties, graphene has not been used for EBFCs as frequently as carbon nanotubes, another nanoscale carbon allotrope. This review focuses on current research progress in graphene-based electrodes, including electrodes modified with graphene derivatives and graphene composites, as well as free-standing graphene electrodes. Particular features of graphene-based electrodes such as high conductivity, mechanical flexibility and high porosity for bioelectrochemical applications are highlighted. Reports on graphene-based EBFCs from the last five years are summarized, and perspectives for graphene-based EBFCs are offered.

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基于石墨烯的酶促生物燃料电池的开发：综述。

酶促生物燃料电池（EBFC）由于在温和条件下具有从多种燃料中收集能量的潜力，因此受到越来越多的关注。有效的生物电极的制造对于EBFC的实际应用至关重要。石墨烯具有独特的理化特性，使其成为构建EBFC的有吸引力的材料。尽管具有这些令人鼓舞的特性，但石墨烯并未像另一种纳米级碳同素异形体碳纳米管那样频繁地用​​于EBFC。这篇综述着重于石墨烯基电极的当前研究进展，包括用石墨烯衍生物和石墨烯复合材料改性的电极，以及独立式石墨烯电极。石墨烯基电极的特殊功能，例如高电导率，突出了生物电化学应用的机械柔韧性和高孔隙率。总结了过去五年中基于石墨烯的EBFC的报告，并提供了基于石墨烯的EBFC的观点。