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Polyvinyl alcohol-based materials encapsulating carvacrol obtained by solvent casting and electrospinning
Reactive & Functional Polymers ( IF 4.5 ) Pub Date : 2020-04-19 , DOI: 10.1016/j.reactfunctpolym.2020.104603
Alina Tampau , Chelo González-Martínez , Amparo Chiralt

Carvacrol has been encapsulated in polyvinyl alcohol (PVA) matrices by electrospinning and casting. Aqueous solutions containing 15% PVA and 15% carvacrol with respect to polymer have been used, containing or not Tween 85 at 0.3 g/100 g carvacrol. Electrospun mats exhibited beads and thin fibres which became thinner and interrupted when carvacrol was present and retained up to 83% of this compound. The encapsulation efficiency in the electrospun mats decreased in the presence of surfactant, reaching values similar to those of casting (75–77%). The electrospun, surfactant free material was practically amorphous with 40% of the total carvacrol non-thermally releasable. In contrast, when surfactant was present and in cast material, with 40% crystallinity, the strongly bonded carvacrol ratio decreased. Specific PVA - phenolic hydroxyl interactions played an important role in the degree of carvacrol retention in the matrices, which depended on surfactant's presence and processing method.



中文翻译:

通过溶剂浇铸和静电纺丝得到的聚乙烯醇类材料,其封装香芹酚

香芹酚已通过静电纺丝和浇铸法封装在聚乙烯醇(PVA)基质中。已经使用相对于聚合物含有15%PVA和15%香芹酚的水溶液,其含有或不含有0.3g / 100g香芹酚的Tween 85。电纺垫呈现出珠粒和细纤维,当存在香芹酚时会变细并中断,并保留高达83%的该化合物。在表面活性剂存在下,电纺垫的封装效率降低,达到与铸造相似的值(75-77%)。电纺丝,不含表面活性剂的材料实际上是无定形的,总香芹酚的40%是不可热释放的。相反,当表面活性剂存在于铸造材料中时,结晶度为40%时,强键香芹酚比率降低。

更新日期:2020-04-19
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