Copper‐Catalyzed Aerobic Oxidative Amination of Indole Derivatives via Single‐Electron Transfer,ChemCatChem

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Copper‐Catalyzed Aerobic Oxidative Amination of Indole Derivatives via Single‐Electron Transfer
ChemCatChem ( IF 3.8 ) Pub Date : 2020-04-15 , DOI: 10.1002/cctc.202000284
Peizheng Zhao ₁ , Ke Wang ₁ , Yuanyuan Yue ₁ , Junli Chao ₁ , Yaqing Ye ₁ , Qinghu Tang ₁ , Jianming Liu ₁

Affiliation

An efficient and clean approach for the oxidative amination of indole derivatives with phenothiazines is developed under copper‐catalyzed aerobic conditions. The reaction is carried out vi a the cross‐coupling of indole radical cation and phenothiazine radical in air. This approach offers a new perspective in the application of phenothiazine as a nitrogen group source for C−N bond formation reactions.

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