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Copper ferrite nanoparticles catalyzed formation of β-Ketophosphonates via oxyphosphorylation of styrenes with H-phosphonates: A DFT study on UV–vis absorption spectra
Catalysis Communications ( IF 3.4 ) Pub Date : 2020-04-11 , DOI: 10.1016/j.catcom.2020.106015
Firouz Matloubi Moghaddam , Maryam Daneshfar , Reza Azaryan , Jean-Luc Pirat

Typical copper ferrite nanoparticles (CuFe2O4) were used as a catalyst for one-pot synthesis of β-ketophosphonates via the reaction of alkenes with H-phosphonates under conventional heating conditions. The catalyst was prepared by using the coprecipitation method and was analyzed by physiochemical techniques. By using this catalyst system, several types of useful and new β-ketophosphonate products were obtained in very good to excellent yields under optimized reaction conditions in a novel way. Furthermore, the catalyst is recyclable and reusable from the reaction.



中文翻译:

铁酸铜纳米颗粒通过苯乙烯与H-膦酸酯的氧磷酸化催化β-酮膦酸酯的形成:DFT研究UV-vis吸收光谱

典型的铁氧体铜纳米颗粒(CuFe 2 O 4)被用作在常规加热条件下通过烯烃与H-膦酸酯反应一锅合成β-酮膦酸酯的催化剂。使用共沉淀法制备催化剂,并通过理化技术进行分析。通过使用这种催化剂体系,在优化的反应条件下以新颖的方式获得了几种非常有用的新型β-酮膦酸酯产品。此外,催化剂可从反应中回收和再利用。

更新日期:2020-04-13
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