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An experimental investigation of the corrosive influence of SO2 relative to H2SO4 of marine engine cylinder liners
Lubrication Science ( IF 1.8 ) Pub Date : 2020-01-08 , DOI: 10.1002/ls.1492
Lars Kjemtrup 1 , Rasmus F. Cordtz 1 , Michael V. Jensen 1 , Jesper Schramm 1
Affiliation  

The present study investigates the corrosive influence of SO2 on cylinder liner wear relative to H2SO4. Several charge gases with different concentrations of SO2, H2SO4, and H2O in air are fed to a motored light duty test engine that operates at 98 revolutions per minute (rpm) in order to resemble the corrosive combustion gas and cycle speed of large low‐speed two‐stroke marine engines. When the trapped cylinder gas is compressed, the H2SO4 and H2O vapours can condense on the oil wetted liner surface, and the SO2 can be absorbed in the oil film. Hereby the liner surface may be exposed to a corrosive attack. A blend of a base oil and a commercial marine engine cylinder lubrication oil is used in the experiments. During testing, oil samples are extracted from the engine and subsequently analysed for iron and sulphur accumulation (using an energy dispersive X‐ray fluorescence spectrometer) in order to couple cylinder liner wear with the amount of SO2, H2SO4, and H2O in the charge gas. In contrast to H2SO4, the wear of SO2 is weak (if any), although the SO2 accumulates/reacts considerably in the lube oil. The highest wear rates are found at elevated H2O concentrations.

中文翻译:

SO2对H2SO4腐蚀对船用发动机汽缸套影响的实验研究

本研究研究了SO 2相对于H 2 SO 4的腐蚀对气缸套磨损的影响。将几种空气中SO 2,H 2 SO 4和H 2 O浓度不同的充气气体送入电动轻负荷试验发动机,该发动机以每分钟98转(rpm)的速度运行,以类似于腐蚀性燃烧气体和循环大型低速二冲程船用发动机的转速。当捕获的气缸气体被压缩时,H 2 SO 4和H 2 O蒸气可在油浸湿的衬套表面上冷凝,而SO 2可被油膜吸收。因此,衬里表面可能受到腐蚀侵蚀。实验中使用了基础油和商用船用发动机气缸润滑油的混合物。在测试过程中,从发动机提取机油样品,然后分析铁和硫的积累(使用能量色散X射线荧光光谱仪),以便将汽缸套磨损量与SO 2, H 2 SO 4和H 2澳电荷气体英寸 与H 2 SO 4相比,SO 2的磨损较弱(如果有),尽管SO 2在润滑油中大量积聚/反应。H 2 O浓度升高时,磨损率最高。
更新日期:2020-01-08
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