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Fluorinated Carbonates as New Diluents for Extraction and Separation of f-Block Elements
Solvent Extraction and Ion Exchange ( IF 1.8 ) Pub Date : 2020-01-14 , DOI: 10.1080/07366299.2019.1708004
Petr Distler 1 , Miriam Mindová 1 , Jan John 1 , Vasilij A. Babain 2 , Mikhail Yu. Alyapyshev 2 , Lyudmila I. Tkachenko 3 , Ekaterina V. Kenf 3 , Laurence M. Harwood 4 , Ashfaq Afsar 4
Affiliation  

The fluorinated carbonate BK-1 solvent was studied as a diluent in extraction systems with different extracting agents – CMPO, THDGA, CyMe4-BTBP, and CyMe4-BTPhen, which are the most promising molecules for separation of minor actinides and lanthanides. Dependence of the extraction properties of the system on the concentrations of HNO3 or extracting compound, kinetics of trivalent metal extraction and extraction of the ions by neat diluent (without the addition of extracting agent) were investigated. Based on the obtained results, BK-1 is a promising candidate diluent for f-block metal separation.



中文翻译:

氟化碳酸盐作为新的稀释剂,用于f族元素的萃取和分离

氟化碳酸盐BK-1溶剂在具有不同萃取剂CMPO,THDGA,CyMe 4 -BTBP和CyMe 4 -BTPhen的萃取系统中作为稀释剂进行了研究,这是分离次minor系元素和镧系元素最有希望的分子。研究了系统萃取性质对HNO 3或萃取化合物浓度,三价金属萃取动力学和纯稀释剂(不添加萃取剂)萃取离子的动力学的影响。基于所获得的结果,BK-1是用于f-嵌段金属分离的有希望的候选稀释剂。

更新日期:2020-04-20
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