ABSTRACT Experimental solubilities have been determined by spectrophotometric methods for 1-chloro-4-bromobenzene, 1,4-dibromobenzene, 1,4-dichloro-2-nitrobenzene, benzoic acid, 4-nitrobenzoic acid, 3,5-dinitrobenzoic acid, 2-methoxybenzoic acid, 4-methoxybenzoic acid, 3-chlorobenzoic acid, 3,5-dinitro-2-methylbenzoic acid, 2-methylbenzoic acid, 3-methylbenzoic acid, 3,4-dichlorobenzoic acid, benzoin, 4-tert-butylbenzoic acid, 4-chlorobenzoic acid, 3,4-dimethoxybenzoic acid, 3,4,5-trimethoxybenzoic acid and o-acetoacetaniside dissolved in 2-ethyl-1-hexanol at 298.15 K. Our experimental measurements, combined with published solubility data retrieved from the published chemical and engineering literature, were used to derive Abraham model correlations for solute transfer into 2-ethyl-1-hexanol from both water and from the gas phase. The derived Abraham model correlations were found to back-calculate the measured experimental values to within ±0.12 log units (or less).

中文翻译：

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基于测量的溶解度比，将溶质从水相和气相转化为 2-乙基-1-己醇的 Abraham 模型相关性的发展

摘要 通过分光光度法测定了 1-氯-4-溴苯、1,4-二溴苯、1,4-二氯-2-硝基苯、苯甲酸、4-硝基苯甲酸、3,5-二硝基苯甲酸、2 -甲氧基苯甲酸、4-甲氧基苯甲酸、3-氯苯甲酸、3,5-二硝基-2-甲基苯甲酸、2-甲基苯甲酸、3-甲基苯甲酸、3,4-二氯苯甲酸、安息香、4-叔丁基苯甲酸, 4-氯苯甲酸、3,4-二甲氧基苯甲酸、3,4,5-三甲氧基苯甲酸和邻乙酰乙醋在 298.15 K 溶解在 2-乙基-1-己醇中。已发表的化学和工程文献，用于推导出从水和气相中将溶质转移到 2-乙基-1-己醇的 Abraham 模型相关性。发现衍生的 Abraham 模型相关性将测量的实验值反向计算到 ±0.12 log 单位（或更少）内。