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Mesoporous cobalt–cobalt phosphide electrocatalyst for water splitting
Materials Today Energy ( IF 9.0 ) Pub Date : 2020-03-05 , DOI: 10.1016/j.mtener.2020.100398
E. Loni , M.H. Siadati , A. Shokuhfar

As a sustainable hydrogen/oxygen production method for the near future, water splitting is still dependent on the appropriate catalysts for acceptable efficiency. Here, for the first time, using silica template, a mesoporous cobalt-cobalt phosphide (Meso-Co/Co2P) electrocatalyst was produced. For investigating its structure, composition, and morphology, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDS) analyses were accomplished. Chronoamperometry, cyclic and linear sweep voltammetry studies exhibited excellent electrocatalytic activity. It needed only an overpotential of 57 mV to produce a 10 mA cm−2 of anodic current density. A water electrolyzer with Meso-Co/Co2P as both anode and cathode in an alkaline medium generated a current density of 10 mA cm−2 at the potential of 1.57 V.



中文翻译:

介孔钴-磷化钴电分解水催化剂

作为在不久的将来可持续的氢气/氧气生产方法,为了达到可接受的效率,水分解仍取决于适当的催化剂。在此,首次使用二氧化硅模板制备了介孔钴-钴磷化物(Meso-Co / Co 2 P)电催化剂。为了研究其结构,组成和形态,完成了X射线衍射(XRD),X射线光电子能谱(XPS),扫描电子显微镜(SEM)和能量色散X射线能谱(EDS)分析。计时安培法,循环伏安法和线性扫描伏安法研究显示出优异的电催化活性。它仅需要57 mV的超电势即可产生10 mA cm -2的阳极电流密度。具有Meso-Co / Co 2的水电解槽在碱性介质中作为阳极和阴极的P在1.57 V的电势下产生10 mA cm -2的电流密度。

更新日期:2020-03-05
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