A simple low-cost cetyltrimethylammonium bromide (CTAB) assisted step-wise metal displacement plating method was used to prepare noble-and noble-metal free Ni/Fe/Pd, Ni/Fe/Ag and Ni/Fe/Cu nickel based nanocatalysts for the hydrogen production from complete hydrazine decomposition in basic solution at mild temperature. Pd/Ag/Ni was prepared by seedless method. Compared to the mono-metallic (Ag⁰, Pd⁰, Fe⁰, Ni⁰ and Cu⁰) and bi-metallic (Pd/Ag, Ag/Ni and Ni/Fe), the tri-metallic catalyst exhibits higher catalytic performance towards hydrazine decomposition. The nessler's reagent was used to detect the formation of ammonia during hydrazine dehydrogenation. The effect of [catalyst], [hydrazine], [NaOH] and temperature were determined on hydrogen generation by using Ni/Fe/Pd. The generation of hydrogen follows excellent first-order kinetics with [hydrazine]. The activation energies were determined to be 32.1, 42.3, 44.6 and 75.9 kJ/mol for Ni/Fe/Pd, Ni/Fe/Ag, Ni/Fe/Cu and Pd/Ag/Ni, respectively. Noble-metal nickel based Ni/Fe/Pd nanocatalyst shows better catalytic efficiency and hydrogen selectivity. The durability of Ni/Fe/Pd provides evidence to excellent catalytic degree for five kinetic runs. The morphology of Ni/Fe/Pd was determined by using FESEM, EDX, TEM, XRD and UV–visible spectroscope. Hydrazine dehydrogenation mechanism proposed, which follows the following rate-law:

$-\frac{d\left[hydrazine\right]}{dt}=\frac{k_1{K}_{ad}O{H}^{-}]Ni@Fe@Pd]{[N{H}_2-N{H}_2]}_T}{1+\frac{K_b}{\left[O{H}^{-}\right]}+K_{ad}{[N{H}_2-N{H}_2]}_T}$

采用一种简单的低成本十六烷基三甲基溴化铵（CTAB）辅助的逐步金属置换电镀方法，制备了无贵金属和无贵金属的Ni / Fe / Pd，Ni / Fe / Ag和Ni / Fe / Cu镍基纳米催化剂。在温和的温度下在碱性溶液中肼完全分解产生的氢气。Pd / Ag / Ni采用无籽法制备。与单金属（Ag ⁰，Pd ⁰，Fe ⁰，Ni ⁰和Cu ⁰）和双金属（Pd / Ag，Ag / Ni和Ni / Fe）时，三金属催化剂对肼分解表现出更高的催化性能。塞纳氏试剂用于检测肼脱氢过程中氨的形成。通过使用Ni / Fe / Pd确定了[催化剂]，[肼]，[NaOH]和温度对产氢的影响。氢的生成与[肼]遵循出色的一级动力学。对于Ni / Fe / Pd，Ni / Fe / Ag，Ni / Fe / Cu和Pd / Ag / Ni，活化能分别确定为32.1、42.3、44.6和75.9 kJ / mol。贵金属镍基Ni / Fe / Pd纳米催化剂表现出更好的催化效率和氢选择性。Ni / Fe / Pd的耐久性为五次动力学运行提供了出色的催化度证据。Ni / Fe / Pd的形貌通过FESEM，EDX，TEM，XRD和紫外可见光谱仪。提出了肼脱氢机理，其遵循以下速率规律：

$-\frac{d\left[Hÿd\mathrm{[R}\mathrm{一种}ž\mathrm{一世}ñË\right]}{dŤ}=\frac{{ķ}_{\mathrm{1个}}{ķ}_{\mathrm{一种}d}ØH^{-}]ñ\mathrm{一世}@FË@Pd]{[ñH_2-ñH_2]}_{Ť}}{\mathrm{1个}+\frac{{ķ}_b}{\left[ØH^{-}\right]}+{ķ}_{\mathrm{一种}d}{[ñH_2-ñH_2]}_{Ť}}$