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Riboflavin Is Directly Involved in N-Dealkylation Catalyzed by Bacterial Cytochrome P450 Monooxygenases.
ChemBioChem ( IF 2.6 ) Pub Date : 2020-04-03 , DOI: 10.1002/cbic.202000071
Chengchang Zhang 1 , Meiling Lu 1 , Lin Lin 2 , Zhangjian Huang 1 , Rongguang Zhang 2 , Xuri Wu 1 , Yijun Chen 1
Affiliation  

Direct transfer: Riboflavin directly transfers electrons to bacterial cytochrome P450 monooxygenases in an oxidative N‐dealkylation. A new mechanism for the electron‐transfer process is proposed that could be generally applicable to numerous P450‐like monooxygenases that lack the reductase domain.
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中文翻译:

核黄素直接参与细菌细胞色素P450单加氧酶催化的N-脱烷基反应。

直接转移:核黄素通过氧化性N-脱烷基直接将电子转移到细菌细胞色素P450单加氧酶。提出了一种电子转移过程的新机制,该机制通常可用于许多缺乏还原酶结构域的P450样单加氧酶。
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更新日期:2020-04-03
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