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Catecholate‐Based Helicates
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2020-04-02 , DOI: 10.1002/ejic.202000255
Markus Albrecht 1
Affiliation  

Catechol is a bidentate ligand for metal coordination which is well suited for the formation of helicates and related metallosupramolecular complexes. The development of the self‐assembly and stereochemistry of helicates based on catechol ligands in the last 25 years is discussed. Unsaturated, heteronuclear and hierarchical helicates as well as molecular switches based on catecholate helicates are covered.

中文翻译:

基于儿茶酚的螺旋

邻苯二酚是用于金属配位的双齿配体,非常适合于形成螺旋体和相关的金属超分子复合物。讨论了过去25年基于邻苯二酚配体的螺旋分子自组装和立体化学的发展。涵盖了不饱和,异核和分级螺旋结构以及基于儿茶酚螺旋结构的分子开关。
更新日期:2020-04-02
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