Metal-Organic Frameworks as a Versatile Platform for Proton Conductors.,Advanced Materials

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Metal-Organic Frameworks as a Versatile Platform for Proton Conductors.
Advanced Materials ( IF 27.4 ) Pub Date : 2020-04-03 , DOI: 10.1002/adma.201907090
Yingxiang Ye _{1,

2} , Lingshan Gong ₁ , Shengchang Xiang ₁ , Zhangjing Zhang ₁ , Banglin Chen ₂

Affiliation

Metal-organic frameworks (MOFs) are an intriguing type of crystalline porous materials that can be readily built from metal ions or clusters and organic linkers. Recently, MOF materials, featuring high surface areas, rich structural tunability, and functional pore surfaces, which can accommodate a variety of guest molecules as proton carriers and to systemically regulate the proton concentration and mobility within the available space, have attracted tremendous attention for their roles as solid electrolytes in fuel cells. Recent advances in MOFs as a versatile platform for proton conduction in the field of humidity condition proton-conduction, anhydrous atmosphere proton-conduction, single-crystal proton-conduction, and including MOF-based membranes for fuel cells, are summarized and highlighted. Furthermore, the challenges, future trends, and prospects of MOF materials for solid electrolytes are also discussed.

中文翻译：

金属有机框架作为质子导体的多功能平台。

金属有机骨架（MOF）是一种有趣的结晶多孔材料，可以很容易地由金属离子或金属簇和有机连接基构建。最近，MOF材料具有高的表面积，丰富的结构可调性和功能性孔表面，可以容纳各种客体分子作为质子载体，并在可用空间内系统地调节质子浓度和迁移率，因此受到了极大的关注。在燃料电池中用作固体电解质。概述并突出了MOF作为湿度条件质子传导，无水大气质子传导，单晶质子传导以及包括基于MOF的燃料电池膜领域中质子传导的通用平台的最新进展。此外，挑战，未来趋势，

更新日期：2020-04-03

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