Abstract A new complex formulated as [Mn(H2O)6][Mn2(ett)6]·0.5H2O (1) has been synthesized from 5-(ethylthio)-1H-tetrazole) (Hett) andMn(OAc)2·4H2O. The crystal structure is composed of one [Mn(H2O)6] 2+ cation and an [Mn2(ett)6] 2– anionic chain. Two Mn(II) ions are bridged by μ2-ett – ligands to give [Mn2(ett)6] 2– anionic chains, which is balanced by cationic part of [Mn(H2O)6] 2+ in charge. The hydrogen bonds between anionic/cationic units play an important role in the formation of three-dimensional (3-D) supramolecular structure of 1. Magnetic measurements of 1 exhibit an interesting spin canting behavior and long-range magnetic ordering. Graphical Abstract

中文翻译：

---

由 5-(乙硫基)-1H-四唑桥接的阴离子 Mn(II) 链显示自旋倾斜和长程磁排序的共存

摘要 以 5-(乙硫基)-1H-四唑) (Hett) 和 Mn(OAc)2·4H2O 为原料合成了一种新的配合物 [Mn(H2O)6][Mn2(ett)6]·0.5H2O (1) . 晶体结构由一个 [Mn(H2O)6] 2+ 阳离子和一个 [Mn2(ett)6] 2- 阴离子链组成。两个 Mn(II) 离子通过 μ2-ett – 配体桥接形成 [Mn2(ett)6] 2– 阴离子链，该链由带电荷的 [Mn(H2O)6] 2+ 的阳离子部分平衡。阴离子/阳离子单元之间的氢键在 1 的三维 (3-D) 超分子结构的形成中起着重要作用。 1 的磁测量显示出有趣的自旋倾斜行为和长程磁排序。图形概要