Sesquiterpene synthases for bungoene, pentalenene and epi-isozizaene from Streptomyces bungoensis.,Organic & Biomolecular Chemistry

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Sesquiterpene synthases for bungoene, pentalenene and epi-isozizaene from Streptomyces bungoensis.
Organic & Biomolecular Chemistry ( IF 2.9 ) Pub Date : 2020-04-02 , DOI: 10.1039/d0ob00606h
Lukas Lauterbach ₁ , Jeroen S Dickschat ₁

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A sesquiterpene synthase from Streptomyces bungoensis was characterised and produces the new compound bungoene. The enzyme mechanism was deeply investigated using isotopically labelled substrates. Two other enzymes from S. bungoensis made epi-isozizaene and pentalenene. Synthetic oxidative chemistry towards structurally related fusagramineol and pentalenal was explored.

中文翻译：

来自松果链霉菌的松香萜烯合成物，用于丁香烯，戊烯和表异异氮烯。

表征了来自邦戈链霉菌的倍半萜烯合酶并产生新的化合物邦戈烯。使用同位素标记的底物对酶机理进行了深入研究。从其他两种酶S. bungoensis制成外延-isozizaene和pentalenene。探索了与结构相关的岩藻糖醇和戊烯醛的合成氧化化学。

更新日期：2020-04-02

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