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Photovoltaic Application of Rice Flake-Shaped ZnO Nanostructures
Journal of Electronic Materials ( IF 2.2 ) Pub Date : 2020-02-25 , DOI: 10.1007/s11664-020-08008-x
Gautam E. Unni , V. N. Vineeth , G. S. Anjusree , Sajini Vadukumpully , V. P. Mahadevan Pillai , A. Sreekumaran Nair , S. Suresh

Rice flake-shaped zinc oxide nanocrystallites were synthesized through a polymer-assisted, one-step hydrothermal route with an average size of 200–600 nm. The role of polymer concentration in the evolution of the nanostructure was evaluated, and the material was characterized using x-ray diffraction, electron microscopy, x-ray photoelectron spectroscopy, and ultraviolet–visible (UV–Vis) spectroscopy. The two-dimensional (2D) nanoflakes were demonstrated as promising photoanode material for dye-sensitized solar cells. Compared with hydrothermally prepared zinc oxide nanoparticles, the rice flake-shaped crystallites exhibited higher dye loading and light-scattering ability, which elicited a substantial increase in the light conversion efficiency. Thus, a fabricated solar cell with an active area of of 0.25 cm2 was provided with a niobium pentoxide blocking layer through radio frequency magnetron sputter coating at the zinc oxide/transparent conducting oxide interface to boost the efficiency up to 7.09% from 5.72% under 1.5-AM conditions.



中文翻译:

稻片状ZnO纳米结构的光伏应用

稻片状氧化锌纳米晶体是通过聚合物辅助的一步水热法合成的,平均粒径为200-600 nm。评估了聚合物浓度在纳米结构演变中的作用,并使用X射线衍射,电子显微镜,X射线光电子能谱和紫外可见(UV-Vis)光谱对材料进行了表征。二维(2D)纳米薄片被证明是用于染料敏化太阳能电池的有希望的光阳极材料。与水热法制备的氧化锌纳米粒子相比,稻片状微晶具有较高的染料负载量和光散射能力,从而大大提高了光转换效率。因此,制造了具有0.25cm 2的有效面积的太阳能电池。 通过在射频氧化锌/透明导电氧化物界面处的射频磁控溅射镀膜在氧化锌/透明导电氧化物界面上提供五氧化二铌阻挡层,以将效率从1.5-AM条件下的5.72%提高到7.09%。

更新日期:2020-04-21
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