In this study, the catalytic activity of the mesoporous SBA-15 supported Ni–Al, Ni–Zr, and Ni–Ti catalysts prepared by an impregnation method were investigated in dry reforming of methane. In addition, Al incorporated SBA-15 (Al–SBA-15) materials used as catalyst support were synthesized following a one-pot hydrothermal route in three different conditions: synthesis in the presence of only HCl, only NaCl, and both HCl and NaCl (denoted as A, S, and B, respectively). All catalysts were characterized by XRD, N₂ adsorption-desorption isotherms, ICP-OES, DRIFTS, SEM, TEM-EDX and TGA techniques before and/or after reaction tests. Among Al, Zr, and Ti impregnated catalysts, Ni–Al impregnated catalyst showed the highest activity in dry reforming of methane. According to activity test results, Al–SBA-15 supported Ni catalyst prepared by the one-pot hydrothermal route in the presence of both HCl and NaCl showed the best catalytic activity with high methane (81%) and carbon dioxide conversion (88%) values at 750 °C. The highest H₂ and CO selectivity values were obtained with the same catalyst with an H₂/CO molar ratio of 0.80. Therefore, these results showed that partial Al (0.11%) incorporated into the structure of SBA-15 was sufficient to improve the catalytic activity of the catalyst in dry reforming of methane.

在这项研究中，研究了通过浸渍法制备的介孔SBA-15负载的Ni-Al，Ni-Zr和Ni-Ti催化剂在甲烷干重整中的催化活性。此外，在三种不同条件下，按照一锅法热液路线，合成了用作催化剂载体的掺铝SBA-15（Al–SBA-15）材料：仅在HCl，仅NaCl以及HCl和NaCl的存在下进行合成（分别表示为A，S和B）。所有催化剂均通过XRD，N ₂表征反应测试之前和/或之后的吸附-解吸等温线，ICP-OES，DRIFTS，SEM，TEM-EDX和TGA技术。在Al，Zr和Ti浸渍的催化剂中，Ni-Al浸渍的催化剂在甲烷干重整中表现出最高的活性。根据活性测试结果，在HCl和NaCl的存在下，通过一锅水热法制备的Al–SBA-15负载的Ni催化剂表现出最佳的催化活性，其中甲烷含量高（81％），二氧化碳转化率高（88％）值在750°C。使用具有H ₂的相同催化剂可获得最高的H ₂和CO选择性值/ CO摩尔比为0.80。因此，这些结果表明，掺入SBA-15结构中的部分Al（0.11％）足以改善催化剂在甲烷干重整中的催化活性。