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Pt nanowire/Ti3C2Tx-CNT hybrids catalysts for the high performance oxygen reduction reaction for high temperature PEMFC
International Journal of Hydrogen Energy ( IF 8.1 ) Pub Date : 2020-04-01 , DOI: 10.1016/j.ijhydene.2020.03.068
Ranran Wang , Zhou Chang , Zhongwei Fang , Tao Xiao , Zuolei Zhu , Bin Ye , Chenxi Xu , Jigui Cheng

The activity of catalyst could be enhanced by the temperature rising, so it is a suitable way to reduce the noble metal loading for the catalyst. However, the corrosion of carbon supports will be remarkable in the high temperature proton exchange membrane fuel cells (HT-PEMFC, >100 °C). This report demonstrated a novel Ti3C2Tx and CNT hybrid material as the catalytic support, and Pt nanowires (Pt NWs) is loaded on the hybrid support to construct the catalyst for HT-PEMFC. The Pt NWs/Ti3C2Tx-CNT performs higher electrochemical activity, better stability than that of commercial Pt/C. The mass activity and specific activity of Pt NWs/Ti3C2Tx-CNT catalysts are 3.89 and 3.02 times as that of Pt/C, respectively. The power densities of HT-PEMFC showed 155.4 mW cm−2 and 182 mW cm−2 at 150 and 180 °C, respectively.



中文翻译:

Pt纳米线/ Ti 3 C 2 T x -CNT杂化催化剂,用于高温PEMFC的高效氧还原反应

温度升高可以提高催化剂的活性,因此是降低催化剂中贵金属负载量的合适方法。但是,碳质载体的腐蚀在高温质子交换膜燃料电池(HT-PEMFC,> 100°C)中会很明显。该报告证明了新型的Ti 3 C 2 T x和CNT杂化材料作为催化载体,并且Pt纳米线(Pt NWs)负载在杂化载体上以构建HT-PEMFC的催化剂。Pt NWs / Ti 3 C 2 T x -CNT比市售Pt / C具有更高的电化学活性和更好的稳定性。Pt NWs / Ti 3 C 2的质量活度和比活度T x -CNT催化剂分别是Pt / C的3.89和3.02倍。HT-PEMFC的功率密度在150和180°C下分别显示为155.4 mW cm -2和182 mW cm -2

更新日期:2020-04-01
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