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Temperature-dependent response to C3H7OH and C2H5OH vapors induced by deposition of Au nanoparticles on SnO2/NiO hollow sphere-based conductometric sensors
Sensors and Actuators B: Chemical ( IF 8.0 ) Pub Date : 2020-04-02 , DOI: 10.1016/j.snb.2020.128041
Rapelang G. Motsoeneng , Ioannis Kortidis , Rirhandzu Rikhotso , Hendrik C. Swart , Suprakas Sinha Ray , David E. Motaung

Pure SnO2, SnO2/NiO, and Au-loaded SnO2/NiO hollow spheres with different Au content were synthesized through a 1-step hydrothermal synthesis. The surface morphology and structural as well as chemical composition of the synthesized Au-loaded SnO2/NiO hollow spheres were carefully investigated. The performance of the pure SnO2, SnO2/NiO, and Au-loaded SnO2/NiO gas sensors in the detection of low concentrations of propanol (C3H7OH) and ethanol (C2H5OH) was evaluated. The as-fabricated Au (2.5 wt. %)-loaded SnO2/NiO gas sensors demonstrated enhanced gas sensing characteristics and were highly sensitive, selective, and stable to C2H5OH vapor at a low operating temperature of 75 °C, whereas an improved response to C3H7OH was observed at 150 °C. The results indicated that compared to pure SnO2 and SnO2/NiO, the Au-loaded SnO2/NiO hollow sphere-based sensor exhibited a significant improvement in the gas sensing response at a lower optimum operating temperature. The long-term stability analyses indicated that the Au (2.5 wt. %)-loaded SnO2/NiO sensor was stable even after 35 days. These findings clearly demonstrated the ability of a 2.5 wt. % Au-loaded SnO2/NiO gas sensor to detect C2H5OH and C3H7OH vapors by adjusting the operating temperature suitably.



中文翻译:

Au纳米粒子在基于SnO2 / NiO空心球的电导传感器上沉积引起的对C3H7OH和C2H5OH蒸气的温度依赖性响应

通过一步水热法合成了纯金的SnO 2,SnO 2 / NiO和载金量不同的Au含量的SnO 2 / NiO中空球。仔细研究了合成的Au负载SnO 2 / NiO空心球的表面形貌,结构及化学组成。评估了纯SnO 2,SnO 2 / NiO和载有Au的SnO 2 / NiO气体传感器在检测低浓度丙醇(C 3 H 7 OH)和乙醇(C 2 H 5 OH)中的性能。制成的Au(2.5 wt。%)负载SnO 2/ NiO气体传感器显示出增强的气体传感特性,并且在75°C的低工作温度下对C 2 H 5 OH蒸气具有高灵敏度,选择性和稳定性,而在150° C时观察到对C 3 H 7 OH的响应有所改善C。结果表明,与纯SnO 2和SnO 2 / NiO相比,Au负载SnO 2 / NiO中空球基传感器在较低的最佳工作温度下显示出显着的气体传感响应改善。长期稳定性分析表明,Au(2.5 wt。%)负载的SnO 2/ NiO传感器即使在35天后仍保持稳定。这些发现清楚地证明了2.5wt。%的能力。%Au负载SnO 2 / NiO气体传感器,通过适当调节操作温度来检测C 2 H 5 OH和C 3 H 7 OH蒸气。

更新日期:2020-04-03
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