Towards an Understanding of the “Ambiphilic” Character of Ionic Liquids for Green Synthesis of Chemically Diverse Architectures,Asian Journal of Organic Chemistry

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Towards an Understanding of the “Ambiphilic” Character of Ionic Liquids for Green Synthesis of Chemically Diverse Architectures
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-04-22 , DOI: 10.1002/ajoc.202000065
Arun K. Sinha _{1,

2} , Richa Singh _{1,

3} , Rajesh Kumar _{4,

5}

Affiliation

For over a decade, ionic liquids have been recognized as green solvents and/or catalysts in the chemical world owing to their unique physical/chemical properties resulting in a diverse range of chemical and biochemical transformations. One of the striking features of ionic liquids is their ability to act as an ambiphilic catalyst i. e. dual electrophilic‐nucleophilic activation of the substrate. The complex interplay of hydrogen bonding, Coulomb and Van‐der Waals interactions between the cationic and anionic part of ionic liquid imparts this ambiphilicity to the ionic liquid. Notably, the present review highlights the channelization of this ambiphic characteristic for various organic synthesis along with the understanding of the mechanism involved. Thus, the better understanding of the ambiphilic character of ionic liquid may open a new perspective of ionic liquid research and their use may trigger many unprecedented reactions which otherwise are tedious or complex.

中文翻译：

理解用于绿色多样化学合成建筑的离子液体的“两亲”特性

十多年来，由于离子液体具有独特的物理/化学特性，导致了广泛的化学和生物化学转化，因此在化学领域已被公认为绿色溶剂和/或催化剂。离子液体的显着特征之一是它们充当歧义催化剂的能力。e。底物的双重亲电活化。离子液体的阳离子和阴离子部分之间氢键，库仑和范德华相互作用的复杂相互作用将这种歧义性赋予了离子液体。值得注意的是，本综述着重介绍了各种有机合成的歧义特征的通道化以及对所涉及机制的理解。从而，

更新日期：2020-04-22

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