Coordinatively unsaturated metal sites (open metal sites) in metal-organic frameworks: design and applications.,Chemical Society Reviews

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Coordinatively unsaturated metal sites (open metal sites) in metal-organic frameworks: design and applications.
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2020-04-01 , DOI: 10.1039/c9cs00609e
Ülkü Kökçam-Demir ₁ , Anna Goldman , Leili Esrafili , Maniya Gharib , Ali Morsali , Oliver Weingart , Christoph Janiak

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Metal-organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on the metal ions or cluster nodes have been generated. This review combines for the first time all aspects of OMS in MOFs, starting from different preparation strategies over theoretical studies on the effects of OMS with host-guest interactions up to distinct OMS-MOF applications. In the experimental part the focus of this review is on MOFs with proven OMS formation which are not only invoked but are clearly verified by analytical methods.

中文翻译：

金属有机框架中的不饱和配位金属位点（开放金属位点）：设计和应用。

当已生成金属离子或簇结上的空路易斯酸位点时，金属有机骨架（MOF）可以包含开放金属位点（OMS）或配位不饱和位点（CUS）或开放配位点（OCS）。这篇综述首次结合了MOF中OMS的所有方面，从对OMS与宿主-客体相互作用的影响的理论研究到不同的OMS-MOF应用的理论研究的不同制备策略开始。在实验部分，本文的重点是具有成熟OMS形成的MOF，这些MOF不仅被调用，而且已通过分析方法进行了明确验证。

更新日期：2020-04-01

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