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Cu-Catalyzed three-component coupling reactions using nitriles, 1,3-dienes and silylboranes.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-04-09 , DOI: 10.1039/d0cc01803a
Yuki Matsuda 1 , Yasushi Tsuji , Tetsuaki Fujihara
Affiliation  

This paper reports novel Cu-catalyzed three-component coupling reactions using nitriles, 1,3-dienes and silylboranes. The desired reactions proceed at room temperature and yield β,γ-unsaturated ketones with a (dimethylphenylsilyl)methyl moiety at the α-position. Diverse nitriles participate in the reaction and the corresponding products were obtained in good to high yields with high regioselectivity.

中文翻译:

铜催化的使用腈,1,3-二烯和甲硅烷基硼烷的三组分偶联反应。

本文报道了使用腈,1,3-二烯和甲硅烷基硼烷的新型铜催化三组分偶联反应。所需的反应在室温下进行,得到在α-位带有(二甲基苯基甲硅烷基)甲基的β,γ-不饱和酮。各种腈参与反应,并以高至高收率和高区域选择性获得了相应的产物。
更新日期:2020-04-01
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